Bisphenol A bis(2,3-dihydroxypropyl) ether

Base Information

• Chemical Name: Bisphenol A bis(2,3-dihydroxypropyl) ether
• CAS No.: 5581-32-8
• Molecular Formula: C21H28O6
• Molecular Weight: 376.45
• European Community (EC) Number: 226-975-4
• DSSTox Substance ID: DTXSID10971212
• Nikkaji Number: J225.038A
• Wikipedia: Bis-HPPP
• Wikidata: Q10860355
• Mol file: 5581-32-8.mol

Synonyms:2,2-bis(4-(2,3-dihydroxypropoxy)phenyl)propane;2-bis-DPP cpd

Chemical Property of Bisphenol A bis(2,3-dihydroxypropyl) ether

Chemical Property:

• Melting Point: 91-97 °C
• Boiling Point: 612℃
• PKA: 13.23±0.20(Predicted)
• Flash Point: 324℃
• PSA: 99.38000
• Density: 1.224
• LogP: 1.47650
• Storage Temp.: Hygroscopic, -20°C Freezer, Under inert atmosphere
• Solubility.: Acetonitrile (Slightly), Methanol (Slightly)
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 10
• Exact Mass: 376.18858861
• Heavy Atom Count: 27
• Complexity: 364

Purity/Quality:

98%Min ^*data from raw suppliers

Bisphenol A bis(2,3-dihydroxypropyl) ether ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(C)(C1=CC=C(C=C1)OCC(CO)O)C2=CC=C(C=C2)OCC(CO)O
• Uses: Bisphenol A Bis(2,3-dihydroxypropyl) ether is used as a standard for determining toxic monomers released from polymers of the inner coating of cans.

Technology Process of Bisphenol A bis(2,3-dihydroxypropyl) ether

There total 9 articles about Bisphenol A bis(2,3-dihydroxypropyl) ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

BPA (80-05-7) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → 3-[4-[1-[4-(2,3-dihydroxypropoxy)phenyl]-1-methylethyl]phenoxy]propane-1,2-diol (5581-32-8)

Guidance literature:

With potassium carbonate; Diethyl carbonate; at 110 ℃; for 18h;

Reference yield: 97.2%

4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol (59501-41-6) + bisphenol A diallyl ether (3739-67-1) → C18H22O4 (13634-08-7) + 3-[4-[1-[4-(2,3-dihydroxypropoxy)phenyl]-1-methylethyl]phenoxy]propane-1,2-diol (5581-32-8)

Guidance literature:

With potassium osmate(VI); water; 4-methylmorpholine N-oxide; In tert-butyl alcohol; at 25 ℃; for 43h; Product distribution / selectivity;

Reference yield: 84.0%

bisphenol A diallyl ether (3739-67-1) → 3-[4-[1-[4-(2,3-dihydroxypropoxy)phenyl]-1-methylethyl]phenoxy]propane-1,2-diol (5581-32-8)

Guidance literature:

With potassium osmate(VI); water; 4-methylmorpholine N-oxide; In tert-butyl alcohol; at 25 ℃; for 18h; Product distribution / selectivity;

upstream raw materials:

BPA

4-chloromethyl-[1,3]dioxolan-2-one

2,2-bis-[4-(2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-phenyl]-propane

3-monochloro-1,2-propanediol

Downstream raw materials:

(1-methylethylidene)bis[4,1-phenyleneoxy(2-hydroxy-3,1-propanediyl)] bismethacrylate

C₁₈H₂₁ClO₃

2-[4-(3-chloro-2-hydroxypropyloxy)phenyl]-2-[4-(2,3-dihydroxypropyloxy)phenyl]propane

1-chloro-3-[4-[2-[4-(3-chloro-2-hydroxypropoxy)phenyl] propan-2-yl]phenoxy]propan-2-ol

Refernces

• 1、 -. "METHODS OF MAKING VINYL ESTER RESINS AND STARTING MATERIALS FOR THE SAME". Paragraph 0068; 0069; 0070; 0071. . Retrieved 2017/07/14.
• 2、 -. "Process for manufacturing an alpha-dihydroxy derivative and epoxy resins prepared therefrom". Page/Page column 37-38. . Retrieved 2008/06/13.