Vinyl formate

Base Information

• Chemical Name: Vinyl formate
• CAS No.: 692-45-5
• Molecular Formula: C3H4 O2
• Molecular Weight: 72.0636
• Hs Code.: 2915120000
• European Community (EC) Number: 211-730-6
• NSC Number: 8403
• UNII: LFS2HF6ZYT
• DSSTox Substance ID: DTXSID20219233
• Nikkaji Number: J49.562J
• Wikipedia: Vinyl_formate
• Wikidata: Q65226021
• Mol file: 692-45-5.mol

Synonyms:VINYL FORMATE;692-45-5;ethenyl formate;Formic acid, vinyl ester;Vinyl methanoate;Formic acid, ethenyl ester;Formic acid, ethenylester (9CI);Vinylester kyseliny mravenci;LFS2HF6ZYT;NSC 8403;EINECS 211-730-6;Vinylester kyseliny mravenci [Czech];BRN 1734741;AI3-25335;NSC-8403;4-02-00-00033 (Beilstein Handbook Reference);Formic acid vinyl;UNII-LFS2HF6ZYT;WLN: VHO1U1;GFJVXXWOPWLRNU-UHFFFAOYSA-;DTXSID20219233;NSC8403;MFCD00046142;AKOS030239928;LS-69707;FT-0632817;Q65226021

Chemical Property of Vinyl formate

Chemical Property:

• Vapor Pressure: 387mmHg at 25°C
• Melting Point: 16.85°C
• Refractive Index: n20/D 1.387(lit.)
• Boiling Point: 46-47°C
• Flash Point: 16°C
• PSA: 26.30000
• Density: 0,959 g/cm³
• LogP: 0.93880
• XLogP3: 0.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 72.021129366
• Heavy Atom Count: 5
• Complexity: 40.2

Purity/Quality:

99%, ^*data from raw suppliers

VINYL FORMATE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 11-36/37/38-41-38
• Safety Statements: 3/7-9-16-36/37/39-36-26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=COC=O

Technology Process of Vinyl formate

There total 6 articles about Vinyl formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

D-sorbitol (50-70-4) → tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + TETRAHYDROPYRANE (142-68-7) + 2-methyltetrahydrofuran (96-47-9) + 2,5-dimethyltetrahydrofuran (1003-38-9) + methanol (67-56-1) + propan-1-ol (71-23-8) + 2-Methylcyclopentanone (1120-72-5) + 3-methyl-cyclopentanone (1757-42-2,6195-92-2) + propylene glycol (57-55-6,63625-56-9) + ethanol (64-17-5) + n-hexan-3-ol (623-37-0) + 2-methylpentan-1-ol (105-30-6) + (S)-Ethyl lactate (687-47-8) + pentan-1-ol (71-41-0) + vinyl formate (692-45-5) + n-hexan-2-one (591-78-6) + n-hexan-3-one (589-38-8) + Isopropyl acetate (108-21-4) + 3-Hydroxy-2-pentanone (3142-66-3,113919-08-7) + acetic acid (64-19-7,77671-22-8) + propionaldehyde (123-38-6) + 2-Pentanone (107-87-9) + propionic acid (802294-64-0,79-09-4) + 1-Hydroxy-2-butanone (5077-67-8) + 2,5-hexanedione (110-13-4) + isopropyl alcohol (67-63-0,8013-70-5) + acetone (67-64-1) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) + pentan-3-one (96-22-0) + isobutyric Acid (79-31-2) + butanone (78-93-3) + iso-butanol (78-92-2,15892-23-6) + hexanoic acid (142-62-1) + Isosorbide (652-67-5) + butyric acid (107-92-6) + 2.3-butanediol (513-85-9) + hexan-1-ol (111-27-3) + valeric acid (109-52-4)

Guidance literature:

platinum on carbon; In water; for 3h; Direct aqueous phase reforming;

Reference yield:

formic acid (64-18-6) + acetylene (74-86-2,25067-58-7) → vinyl formate (692-45-5)

Guidance literature:

With mercury(II) diacetate; boric acid; at 10 - 20 ℃;

Reference yield:

formic acid (64-18-6) + vinyl acetate (108-05-4,9003-20-7) → vinyl formate (692-45-5)

Guidance literature:

With phosphoric acid; mercury(II) oxide;

upstream raw materials:

formic acid

vinyl acetate

vinyl n-butyrate

acetylene

Downstream raw materials:

1-butylene

(triphenylphosphine)3(CO)nickelk

acetaldehyde

(CO)2Ni(P(C₆H₁₁-cyclo)3)2

Refernces

• 1、 -. "Novel tin (IV) compounds". . . Retrieved 2008/06/13.