N,N-Dimethylundecylamine

Base Information

• Chemical Name: N,N-Dimethylundecylamine
• CAS No.: 17373-28-3
• Molecular Formula: C13H29N
• Molecular Weight: 199.38
• European Community (EC) Number: 621-478-2
• NSC Number: 359844
• DSSTox Substance ID: DTXSID20276245
• Nikkaji Number: J423.206B
• Wikidata: Q82006657
• Mol file: 17373-28-3.mol

Synonyms:17373-28-3;N,N-dimethylundecan-1-amine;N,N-Dimethylundecylamine;1-Undecanamine, N,N-dimethyl-;N,N-DIMETHYLUNDECYLAMINE, 97;Undecanamine, N,N-dimethyl-;Undecyldimethylamin;undecyldimethylamine;NSC359844;dimethyl(undecyl)amine;SCHEMBL225887;N,N-Dimethyl-1-undecanamine #;DTXSID20276245;STL453820;AKOS006229453;NSC 359844;NSC-359844;N,N-Dimethylundecylamine, purum, >=98.0% (GC)

Chemical Property of N,N-Dimethylundecylamine

Chemical Property:

• Vapor Pressure: 0.0242mmHg at 25°C
• Melting Point: 26°C (estimate)
• Refractive Index: n20/D 1.435(lit.)
• Boiling Point: 248.5 °C at 760 mmHg
• Flash Point: 96.8 °C
• PSA: 3.24000
• Density: 0.796 g/cm³
• LogP: 4.07880
• XLogP3: 5.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 10
• Exact Mass: 199.229999929
• Heavy Atom Count: 14
• Complexity: 99.4

Purity/Quality:

99% ^*data from raw suppliers

N,N-Dimethyl-N-undecylamine 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCN(C)C

Technology Process of N,N-Dimethylundecylamine

There total 10 articles about N,N-Dimethylundecylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

decanecarboxylic acid dimethylamide (6225-09-8) → N,N-dimethylundecylamine (17373-28-3)

Guidance literature:

decanecarboxylic acid dimethylamide; With bis(cyclopentadienyl)dihydrozirconium; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; at 20 ℃; Glovebox; Inert atmosphere;

With hydrogenchloride; In diethyl ether; water; for 2h; Glovebox; Inert atmosphere;

DOI:10.1016/S1872-2067(21)63853-6

Reference yield: 83.0%

methanol (67-56-1) + 1-undecylamine (7307-55-3) → N,N-dimethylundecylamine (17373-28-3)

Guidance literature:

With bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)]; bis[2-(diphenylphosphino)phenyl] ether; lithium tert-butoxide; at 100 ℃; for 24h;

DOI:10.1021/acscatal.5b00606

Reference yield: 77.0%

Dimethyl-undecyl-aminoxid (15178-71-9) → N,N-dimethylundecylamine (17373-28-3)

Guidance literature:

With niobium pentachloride; zinc; In tetrahydrofuran; benzene; at 23 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tet.2009.02.013

upstream raw materials:

bromoundecane

dimethyl amine

1-Decene

carbon monoxide

Downstream raw materials:

triethylamine

dimethyl-n-hexadecyl<10-(p-vinylcarboxanilido)decyl>ammonium bromide

Benzyldimethylundecylammonium chloride

Refernces

• 1、 Han, Bo,Jiao, Haijun,Wu, Lipeng,Zhang, Jiong. "Zirconium-hydride-catalyzed site-selective hydroboration of amides for the synthesis of amines: Mechanism, scope, and application". . p. 2059 - 2067. Retrieved 2021/09/02.
• 2、 Jamil, Md.A.R.,Touchy, Abeda S.,Rashed, Md. Nurnobi,Ting, Kah Wei,Siddiki, S.M.A. Hakim,Toyao, Takashi,Maeno, Zen,Shimizu, Ken-ichi. "N-Methylation of amines and nitroarenes with methanol using heterogeneous platinum catalysts". . p. 47 - 56. Retrieved 2019/02/07.