Dichlorophenylarsine

Base Information

• Chemical Name: Dichlorophenylarsine
• CAS No.: 696-28-6
• Molecular Formula: C6H5 As Cl2
• Molecular Weight: 222.933
• Hs Code.: 2931900023
• European Community (EC) Number: 211-791-9
• UN Number: 1556
• UNII: KK93BBF49U
• DSSTox Substance ID: DTXSID7061011
• Nikkaji Number: J35.219E
• Wikipedia: Phenyldichloroarsine
• Wikidata: Q414342
• Mol file: 696-28-6.mol

Synonyms:phenyldichloroarsine

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Chemical Property of Dichlorophenylarsine

Chemical Property:

• Vapor Pressure: 0.026mmHg at 25°C
• Melting Point: -19°C
• Refractive Index: 1.6386
• Boiling Point: 255.5°C at 760 mmHg
• Flash Point: 114.3°C
• PSA: 0.00000
• Density: 1.652
• LogP: 1.85940
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 221.898425
• Heavy Atom Count: 9
• Complexity: 79.1

Purity/Quality:

Safty Information:

• Pictogram(s): Toxic by ingestion and inhalation, strong irritant to eyes, skin, and tissue.
• Hazard Codes: Toxic by ingestion and inhalation, strong irritant to eyes, skin, and tissue.

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Chemical Weapons
• Canonical SMILES: C1=CC=C(C=C1)[As](Cl)Cl

Technology Process of Dichlorophenylarsine

There total 47 articles about Dichlorophenylarsine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

phenylarsonic acid (98-05-5) → dichlorophenylarsine (696-28-6)

Guidance literature:

With hydrogenchloride; sulfur dioxide; iodine; In water; at 55 ℃; for 6h; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201602491

Reference yield: 64.0%

phenylarsine oxide (637-03-6) → dichlorophenylarsine (696-28-6)

Guidance literature:

With hydrogenchloride; In water; at 60 ℃; for 0.333333h; Inert atmosphere; Schlenk technique;

DOI:10.1039/d0dt01538e

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + benzyl-phenyl-arsinic acid (29427-07-4) → dichlorophenylarsine (696-28-6) + benzyl chloride (100-44-7)

Guidance literature:

upstream raw materials:

triphenyl-arsane

trichlorodiphenylarsorane

phenylarsonic acid

bis-(2-chloro-vinyl)-phenyl-arsine

Downstream raw materials:

2-Phenyl-1,2,3,4-tetrahydro-isoarsinolin

phenyl-arsonous acid dimethyl ester

4-methoxymethyl-2-phenyl-[1,3,2]dioxarsolane

(2-ethylsulfanyl-ethyl)-phenyl-arsinic acid

Refernces

• 1、 Green, Joshua P.,Han, Yang,Kilmurray, Rebecca,McLachlan, Martyn A.,Anthopoulos, Thomas D.,Heeney, Martin. "An Air-Stable Semiconducting Polymer Containing Dithieno[3,2-b:2′,3′-d]arsole". . p. 7148 - 7151. Retrieved 2016.
• 2、 Rakhmatullin,Selyutina,Gavrilov,Musin. "Kinetics of the reactions of [Chloro(phenyl)arsanyl]acetic acid with bromo- and iodoacetic acids". scheme or table. p. 378 - 382. Retrieved 2009/06/28.