(C₆H₅)4C₂₀H₈N₄Fe(CC(O)CH₂C(CH₃)2CH₂C(O))2

Base Information

• Chemical Name: (C₆H₅)4C₂₀H₈N₄Fe(CC(O)CH₂C(CH₃)2CH₂C(O))2
• CAS No.: 103500-99-8
• Molecular Formula: C₆₀H₄₈FeN₄O₄
• Molecular Weight: 944.913
• Mol file: 103500-99-8.mol

Synonyms:(C₆H₅)4C₂₀H₈N₄Fe(CC(O)CH₂C(CH₃)2CH₂C(O))2

Chemical Property of (C₆H₅)4C₂₀H₈N₄Fe(CC(O)CH₂C(CH₃)2CH₂C(O))2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₆H₅)4C₂₀H₈N₄Fe(CC(O)CH₂C(CH₃)2CH₂C(O))2

There total 3 articles about (C₆H₅)4C₂₀H₈N₄Fe(CC(O)CH₂C(CH₃)2CH₂C(O))2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) + (4,4-dimethyl-2,6-dioxo-cyclohexyl)-phenyl-iodonium betaine (35024-12-5) → (C6H5)4C20H8N4FeCl(CC(O)CH2C(CH3)2CH2C(O))*H2O + (C6H5)4C20H8N4Fe(CC(O)CH2C(CH3)2CH2C(O))2 (103500-99-8)

Guidance literature:

With AgClO₄; HCl; water; In methanol; dichloromethane; water; to deaerated soln. of Fe(porphyrin)(Cl) in CH2Cl2 added anhyd. AgClO4, stirred under Ar for 0.5 h at room temp., added to 20 equiv. of iodoniumylide and AgClO4, stirred for 2 h at 20°C, filtered, stirred for0.25 h with MeOH soln. of concd. HCl; org. layer washed with water, dried over Na2SO4, filtered, evapd., chromd. (SiO2, CH2Cl2/ethyl acetate, 95:5), pptd. by addn. of pentane; elem.anal.;

DOI:10.1021/ja00278a039

Reference yield:

[(C6H5)4C20H8N4Fe(CC(O)CH2C(CH3)2CH2C(O))2](1+) (103501-03-7) → (C6H5)4C20H8N4Fe(CC(O)CH2C(CH3)2CH2C(O))2 (103500-99-8)

Guidance literature:

With LiClO₄; In acetonitrile; Electrolysis; spectroelectrochemical redn. of Fe(III) complex (0.4 mM in MeCN, 0.2 M LiClO4) at Pt minigrid electrode (potential: 0 V); not isolated; detected by UV;

DOI:10.1021/ja00278a039

Reference yield:

(4,4-dimethyl-2,6-dioxo-cyclohexyl)-phenyl-iodonium betaine (35024-12-5) + 5,10,15,20-tetraphenyl porphyrin iron (16591-56-3) → (C6H5)4C20H8N4Fe(CC(O)CH2C(CH3)2CH2C(O))2 (103500-99-8)

Guidance literature:

In toluene; addn. of Fe(TPP) to I compd. in deaerated toluene and stirring at 50°C for 0.5 h; purifn. by column chromy. (SiO2, CH2Cl2:CH3COCH3); elem. anal.;

DOI:10.1021/ja00332a077

upstream raw materials:

[(C₆H₅)4C₂₀H₈N₄Fe(CC(O)CH₂C(CH₃)2CH₂C(O))2]⁽¹⁺⁾

meso-tetraphenylporphyrin iron(III) chloride

(4,4-dimethyl-2,6-dioxo-cyclohexyl)-phenyl-iodonium betaine

5,10,15,20-tetraphenyl porphyrin iron

Refernces

• 1、 Battioni, Jean-Paul,Artaud, Isabelle,Dupre, Daniel,Leduc, Philippe,Akhrem, Irena,et al.. "Reaction of a Carbon Equivalent of Iodosylbenzene with Iron-Porphyrins: A Ready Access to N-Alkylporphyrin Complexes Involving Five-Membered Fe-O-C-C-N Metallocycles". . p. 5598 - 5607. Retrieved 2007/10/02.