Allyltriethylgermane

Base Information

• Chemical Name: Allyltriethylgermane
• CAS No.: 1793-90-4
• Molecular Formula: C9H20 Ge
• Molecular Weight: 200.848
• DSSTox Substance ID: DTXSID00170792
• Nikkaji Number: J49.209D
• Wikidata: Q83040812
• Mol file: 1793-90-4.mol

Synonyms:Allyltriethylgermane;1793-90-4;Germanium, triethylallyl-;triethyl(prop-2-enyl)germane;Triethylallyl germane;Triethylallylgermanium;Germane, triethyl-2-propen-1-yl-;Allyltriethyl germane;Germane, allyltriethyl-;C9H20Ge;C9-H20-Ge;Germane, triethyl-2-propenyl-;DTXSID00170792;triethyl(prop-2-en-1-yl)germane;MFCD00156436;LS-71223;FT-0693028

Chemical Property of Allyltriethylgermane

Chemical Property:

• Vapor Pressure: 1.11mmHg at 25°C
• Refractive Index: 1.4594
• Boiling Point: 181-182°C
• Flash Point: 55.5°C
• PSA: 0.00000
• Density: 1 g/cm3
• LogP: 3.68090
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 202.0776784
• Heavy Atom Count: 10
• Complexity: 84.6

Purity/Quality:

99% ^*data from raw suppliers

ALLYLTRIETHYLGERMANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Ge](CC)(CC)CC=C

Technology Process of Allyltriethylgermane

There total 9 articles about Allyltriethylgermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

allylmagnesium bromide (2622-05-1) + triethylchlorogermane (994-28-5) → allyltriethylgermane (1793-90-4)

Guidance literature:

In diethyl ether; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1039/d0dt00557f

Reference yield: 83.0%

triethylgermyltributylstannane (7749-86-2) + allyl bromide (106-95-6) → allyltriethylgermane (1793-90-4)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; for 17h; Product distribution; Ambient temperature; other allylic halides;

DOI:10.1246/cl.1996.697

Reference yield:

tributyl(triethylgermyl)stannane (181476-24-4) + allyl bromide (106-95-6) → tributyltin bromide (1461-23-0) + allyltributylstanane (24850-33-7) + allyltriethylgermane (1793-90-4) + Bromotriethylgermanium (1067-10-3)

Guidance literature:

With triphenylphosphine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In benzene; stirring under N2 at 100 or 80 °C for 10 h gave various yields;

DOI:10.1016/S0022-328X(00)00620-3

upstream raw materials:

triethylgermyltributylstannane

allyl bromide

ethylmagnesium bromide

tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex

Downstream raw materials:

allytriphenyltin

2-allylbenzonitrile

phenyl-(1-phenyl-but-3-enyl)-amine

2-cyano-5,6-diphenylpyrazine

Refernces

• 1、 Nakano, Taichi,Ono, Kazuyoshi,Senda, Yoshiya,Migita, Toshihiko. "Palladium complex-catalyzed germylation of allylic halides using (germyl)stannanes". . p. 313 - 317. Retrieved 2007/10/03.