2-acetyl-2-hydroxycyclopentanone

Base Information

• Chemical Name: 2-acetyl-2-hydroxycyclopentanone
• CAS No.: 1262892-77-2
• Molecular Formula: C₇H₁₀O₃
• Molecular Weight: 142.155
• Mol file: 1262892-77-2.mol

Synonyms:2-acetyl-2-hydroxycyclopentanone

Chemical Property of 2-acetyl-2-hydroxycyclopentanone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-acetyl-2-hydroxycyclopentanone

There total 11 articles about 2-acetyl-2-hydroxycyclopentanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

2-acetylcyclopentanaone (1670-46-8) → 1,3,5-Trioxan (110-88-3) + 4-butanolide (96-48-0) + glutaric anhydride, (108-55-4) + 1,5-pentanedioic acid (110-94-1) + 2-acetyl-2-hydroxycyclopentanone (1262892-77-2) + 2-acetoxycyclopentanone (52789-75-0) + 2-acetyl-2-hydroxymethylcyclopentanone (1167443-17-5) + 2-acetyl-2,3-epoxycyclopentanone (89540-15-8)

Guidance literature:

With oxygen; In acetone; at 20 ℃; for 4h; Irradiation;

DOI:10.1007/s11172-012-0149-8

Reference yield: 20.0%

2-acetylcyclopentanaone (1670-46-8) → glutaric anhydride, (108-55-4) + 1,5-pentanedioic acid (110-94-1) + 5,6-dioxo-n-heptanoic acid (85951-55-9) + 2-acetyl-2-hydroxycyclopentanone (1262892-77-2) + 2-acetoxycyclopentanone (52789-75-0) + 2-acetyl-2,3-epoxycyclopentanone (89540-15-8)

Guidance literature:

With oxygen; In tetrachloromethane; at 20 ℃; for 3h; Irradiation;

DOI:10.1007/s11172-012-0149-8

Reference yield: 11.0%

2-acetylcyclopentanaone (1670-46-8) → 1,3,5-Trioxan (110-88-3) + 4-butanolide (96-48-0) + glutaric anhydride, (108-55-4) + formic acid (64-18-6) + 1,5-pentanedioic acid (110-94-1) + 4-Hydroxy-4-methyl-2-pentanone (123-42-2) + 4-acetoxybutyric acid (26976-72-7) + 5,6-dioxo-n-heptanoic acid (85951-55-9) + 2-acetyl-2-hydroxycyclopentanone (1262892-77-2) + 2-acetoxycyclopentanone (52789-75-0) + 2-acetyl-2-hydroxymethylcyclopentanone (1167443-17-5) + 1,1'-diacetyl-1,1'-bicyclopentyl-2,2'-dione (1426960-55-5) + 2-acetyl-2,3-epoxycyclopentanone (89540-15-8) + acetic acid (64-19-7,77671-22-8)

Guidance literature:

With oxygen; calcium chloride; In acetone; at 57 ℃; for 30h;

DOI:10.1007/s11172-012-0149-8

upstream raw materials:

2-acetylcyclopentanaone

Downstream raw materials:

2-acetoxycyclopentanone

6-acetyltetrahydro-2H-pyran-2-one

Refernces

• 1、 Novikov,Shestak. "Thermal and photochemical oxidation of 2-acetylcyclopentanone with atmospheric oxygen". . p. 1099 - 1110. Retrieved 2013/07/26.