Brilliant green

Base Information

• Chemical Name: Brilliant green
• CAS No.: 633-03-4
• Deprecated CAS: 56730-57-5,70165-37-6,98712-72-2,820975-89-1,1051370-53-6,1051370-53-6,70165-37-6,820975-89-1,98712-72-2
• Molecular Formula: C27H33N2^.HSO4
• Molecular Weight: 482.644
• Hs Code.: 3204 13 00
• European Community (EC) Number: 211-190-1
• NSC Number: 5011
• UNII: G0L543D370
• DSSTox Substance ID: DTXSID1048700
• Wikipedia: Brilliant_green_(dye)
• Wikidata: Q427105
• NCI Thesaurus Code: C83560
• RXCUI: 19698
• Pharos Ligand ID: L3AXXFAZMDPT
• ChEMBL ID: CHEMBL1790039
• Mol file: 633-03-4.mol

Synonyms:(4-(4-(diethylamino)-alpha-phenylbenzylidene)-2,5-cyclohexadien-1-ylidene)diethylammonium sulfate;(4-(p-(diethylamino)-alpha-phenylbenzylidene)-2,5-cyclohexadien-1-ylidene)diethylammonium sulfate;benzenaminium, 4-((4-(dimethylamino)phenyl)(4-(dimethyliminio)-2,5-cyclohexadien-1-ylidene)methyl)-N-ethyl-N,N-dimethyl-, bromide chloride (1:1:1);brilliant green;ethyl green

Chemical Property of Brilliant green

Chemical Property:

• Appearance/Colour: Metallic green crystals
• Vapor Pressure: 0Pa at 25℃
• Melting Point: 180 °C
• Refractive Index: 1.6510 (estimate)
• Boiling Point: 100.0
• PSA: 92.29000
• Density: 1.1016 (rough estimate)
• LogP: 6.48360
• Storage Temp.: Store at RT.
• Solubility.: 100g/l
• Water Solubility.: 100 G/L (25 ºC)
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 7
• Exact Mass: 482.22392874
• Heavy Atom Count: 34
• Complexity: 642

Purity/Quality:

99.9% ^*data from raw suppliers

Brilliant green ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22-36-36/37/38-20/21/22
• Safety Statements: 26-39-36-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Dyes -> Di- and Triaryl Dyes
• Canonical SMILES: CCN(CC)C1=CC=C(C=C1)C(=C2C=CC(=[N+](CC)CC)C=C2)C3=CC=CC=C3.OS(=O)(=O)[O-]
• Uses: Dyeing silk, wool, leather, jute and cotton yellowish-green; manufacture of green ink; biological stain; indicator. Brilliant Green a stain used in bacteriological media.

Technology Process of Brilliant green

There total 7 articles about Brilliant green which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4,4'-(phenylmethylene)bis(N,N-diethylaniline) (82-90-6) → brilliant green (633-03-4)

Guidance literature:

With lead dioxide;

Reference yield:

bis(4-dimethylaminophenyl)phenylmethane (129-73-7) → brilliant green (633-03-4)

Guidance literature:

With hydrogenchloride; lead dioxide; Darstellung;

Reference yield:

Benzotrichlorid (98-07-7) + N,N-diethylaniline (91-66-7) → brilliant green (633-03-4)

Guidance literature:

With zinc(II) chloride;

upstream raw materials:

bis(4-dimethylaminophenyl)phenylmethane

4,4'-(phenylmethylene)bis(N,N-diethylaniline)

Benzotrichlorid

N,N-diethylaniline

Downstream raw materials:

HO₄S^(1-)*C₂₇H₃₃N₂⁽¹⁺⁾*C₈₀H₇₆Cl₄N₁₆O₄

carbon dioxide

N,N-diethyl-para-aminophenole

(4-(diethylamino)phenyl)(phenyl)methanone

Refernces

• 1、 Gupta, Susanta K. Sen,Arvind, Udai. "Carbenium ion-carbinol equilibration for basic triarylmethane dyes: Relative reactivities of dyes in aq. solutions". . p. 998 - 1000. Retrieved 2007/10/02.