DIETHYLDITHIOCARBAMIC ACID LEAD SALT

Base Information

• Chemical Name: DIETHYLDITHIOCARBAMIC ACID LEAD SALT
• CAS No.: 17549-30-3
• Molecular Formula: C10H20 N2 Pb S4
• Molecular Weight: 503.746
• Mol file: 17549-30-3.mol

Synonyms:Lead,bis(diethylcarbamodithioato-S,S')-, (T-4)-; Lead, bis(diethylcarbamodithioato-kS,kS')-, (T-4)- (9CI); Lead, bis(diethyldithiocarbamato)-(6CI,7CI,8CI); Bis(diethyldithiocarbamato)lead;Bis(diethyldithiocarbamato)lead(II); Lead bis(N,N-diethyldithiocarbamate); Leadbis(diethyldithiocarbamate); Lead(II) diethyldithiocarbamate; NSC 141019

Chemical Property of DIETHYLDITHIOCARBAMIC ACID LEAD SALT

Chemical Property:

• Boiling Point: 437.38°C (estimate)
• PSA: 134.68000
• LogP: 2.70500
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 504.02759
• Heavy Atom Count: 17
• Complexity: 219

Purity/Quality:

99%, ^*data from raw suppliers

LEAD DIETHYLDITHIOCARBAMATE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 61-20/22-33-50/53-62
• Safety Statements: 53-45-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)C(=S)S[Pb]SC(=S)N(CC)CC

Technology Process of DIETHYLDITHIOCARBAMIC ACID LEAD SALT

There total 3 articles about DIETHYLDITHIOCARBAMIC ACID LEAD SALT which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lead(II) nitrate + sodium diethyldithiocarbamate trihydrate (20624-25-3) → bis(N,N-diethyldithiocarbamato)lead (17549-30-3)

Guidance literature:

In not given; prepared according to T. Trindade, P. O'Brien, X.-M. Zhang, M. Motevalli, J. Mater. Chem., 1997, 7, 1011;

DOI:10.1002/anie.200705142

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + lead(II) acetate trihydrate (6080-56-4) + diethylamine (109-89-7) → bis(N,N-diethyldithiocarbamato)lead (17549-30-3)

Guidance literature:

carbon disulfide; diethylamine; In methanol; for 0.5h;

lead(II) acetate trihydrate; In methanol; water;

DOI:10.1021/cm504765z

Reference yield:

lead(II) nitrate + sodium N,N-diethyldithiocarbamate (148-18-5) → bis(N,N-diethyldithiocarbamato)lead (17549-30-3)

Guidance literature:

react. of nitrate with dithiocarbamate, described in G. Brauer, Handbuch der Praeparativen Anorganischen Chemie, Vol. 1, Enke-Verlag, Stuttgart (1965), p. 545; recrystn. from CHCl3-ethylene chloride; elem. anal.;

upstream raw materials:

sodium N,N-diethyldithiocarbamate

sodium diethyldithiocarbamate trihydrate

carbon disulfide

lead(II) acetate trihydrate

Downstream raw materials:

bis(N,N-diethyldithiocarbamato)mercury(II)

nickel(II) diethyldithiocarbamate

Refernces

• 1、 Sun, Jianwei,Buhro, William E.. "The use of single-source precursors for the solution-liquid-solid growth of metal sulfide semiconductor nanowires". . p. 3215 - 3218. Retrieved 2008/12/23.