1,3,5-benzenetricarbonyl triazide

Base Information

• Chemical Name: 1,3,5-benzenetricarbonyl triazide
• CAS No.: 347165-20-2
• Molecular Formula: C₉H₃N₉O₃
• Molecular Weight: 285.181
• Mol file: 347165-20-2.mol

Synonyms:1,3,5-benzenetricarbonyl triazide

Chemical Property of 1,3,5-benzenetricarbonyl triazide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3,5-benzenetricarbonyl triazide

There total 6 articles about 1,3,5-benzenetricarbonyl triazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3,5-benzene tris(carbonyl chloride) (4422-95-1) → 1,3,5-benzenetricarbonyl triazide (347165-20-2)

Guidance literature:

With sodium azide; In tetrahydrofuran; water; for 1.5h; cooling;

DOI:10.1021/ja020984n

Reference yield:

benzene-1,3,5-tricarboxylic acid (554-95-0) → 1,3,5-benzenetricarbonyl triazide (347165-20-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 100 percent / SOCl₂ / dimethylformamide / 3 h / Heating

2: sodium azide / tetrahydrofuran; H₂O / 2 h / 0 °C

With thionyl chloride; sodium azide; In tetrahydrofuran; water; N,N-dimethyl-formamide;

DOI:10.1016/j.tet.2007.02.066

Reference yield:

benzene-1,3,5-tricarboxylic acid trihydrazide (36997-31-6) → 1,3,5-benzenetricarbonyl triazide (347165-20-2)

Guidance literature:

With hydrogenchloride; sodium nitrite; In water; at 10 ℃; for 1h;

DOI:10.1080/00397910701227044

upstream raw materials:

1,3,5-benzene tris(carbonyl chloride)

benzene-1,3,5-tricarboxylic acid trihydrazide

benzene-1,3,5-tricarboxylic acid

triethyl benzene-1,3,5-tricarboxylate

Downstream raw materials:

1,3,5-benzenetriisocyanate

Refernces

• 1、 Van Gorp, Judith J.,Vekemans, Jef A. J. M.,Meijer. "C3-symmetrical supramolecular architectures: Fibers and organic gels from discotic trisamides and trisureas". . p. 14759 - 14769. Retrieved 2002.
• 2、 -. "COMPOUNDS, PHARMACEUTICAL COMPOSITIONS AND USE THEREOF AS INHIBITORS OF RAN GTPASE". Paragraph 00103; 00134; 00135. . Retrieved 2019/04/09.
• 3、 -. "COMPOSITIONS FOR, SOLUTIONS FOR, AND METHODS OF USE OF SILOXANE BASED AROMATIC TRISUREAS AS VISCOSIFIERS". Paragraph 0060-0063. . Retrieved 2017/09/02.