tetrakis(2,6-difluorophenyl)porphyrinate^(2-)iron(II)

Base Information

• Chemical Name: tetrakis(2,6-difluorophenyl)porphyrinate^(2-)iron(II)
• CAS No.: 162257-76-3
• Molecular Formula: C₄₄H₂₀F₈FeN₄
• Molecular Weight: 812.504
• Mol file: 162257-76-3.mol

Synonyms:tetrakis(2,6-difluorophenyl)porphyrinate^(2-)iron(II)

Chemical Property of tetrakis(2,6-difluorophenyl)porphyrinate^(2-)iron(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetrakis(2,6-difluorophenyl)porphyrinate^(2-)iron(II)

There total 5 articles about tetrakis(2,6-difluorophenyl)porphyrinate^(2-)iron(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porhpyrinato]-iron(III) chloride (99038-25-2,221335-24-6) → tetrakis(2,6-difluorophenyl)porphyrinate(2-)iron(II) (162257-76-3)

Guidance literature:

With sodium hydrosulfite; In dichloromethane; water; under Ar to soln. (F8TPP)Fe(III)Cl in CH2Cl2 was added aq. sodium hydrosulfite and agitaged with Ar bubbling for 30 min; organic layer was concd. and heptane was added;

DOI:10.1021/ic0105866

Reference yield: 72.0%

hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III) (98716-00-8) → tetrakis(2,6-difluorophenyl)porphyrinate(2-)iron(II) (162257-76-3)

Guidance literature:

With Na₂S₂O₄; In dichloromethane; water; Ar-atmosphere; stirring Fe-complex (in CH2Cl2) with 1 M aq. Na2S2O4 for 30 min; drying of org. layer (MgSO4), concn., pptn. on heptane addn.; elem. anal.;

DOI:10.1021/ic981431+

Reference yield:

{(tetrakis(2,6-difluorophenyl)porphyrin)iron(III)-O2(2-)-copper(II)(tris(2-pyridylmethyl)amine)}(1+) → tetrakis(2,6-difluorophenyl)porphyrinate(2-)iron(II) (162257-76-3)

Guidance literature:

With NH₄OH; In water; byproducts: tris(2-pyridylmethyl)amine; deliberate decompn. in aq. NH4OH soln.;; extraction into CH2Cl2; not isolated, equimolar quantities of iron complex and amine obtained, detected by (1)H NMR spectroscopy;;

upstream raw materials:

[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porhpyrinato]-iron(III) chloride

[Cu(pmea)]B(C₆F₅)4

[Cu(pmap)]B(C₆F₅)4

hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)

Downstream raw materials:

[(tetrakis(2,6-difluorophenyl)porphyrinato)Fe(III)(superoxo)(propionitrile)]

[(tetrakis(2,6-difluorophenyl)porphyrinato)Fe(III)-(O₂^(1-))]

[(5-ortho-O-[(N,N-bis(2-pyridylmethyl)-2-(6-methoxy)pyridinemethanamine)phenyl]-10,15,20-tris(2,6-difluorophenyl)porphine^(2-))Fe(II)Fe(II)-Cl]⁽¹⁺⁾

Refernces

• 1、 Ghiladi,Kretzer,Guzei,Rheingold,Neuhold,Hatwell,Zuberbuehler,Karlin. "(F8TPP)FeII/O2 reactivity studies {F8TPP = tetrakis(2,6-difluorophenyl)porphyrinate(2-)}: Spectroscopic (UV-visible and NMR) and kinetic study of solvent-dependent (Fe/O2 = 1:1 or 2:1) reversible O2-reduction and ferryl formation". . p. 5754 - 5767. Retrieved 2008/10/08.