Butyltriphenylphosphonium chloride

Base Information

• Chemical Name: Butyltriphenylphosphonium chloride
• CAS No.: 13371-17-0
• Molecular Formula: C22H24ClP
• Molecular Weight: 354.859
• Hs Code.: 2931 39 90
• European Community (EC) Number: 236-443-3
• DSSTox Substance ID: DTXSID30884597
• Mol file: 13371-17-0.mol

Synonyms:Butyltriphenylphosphonium chloride;13371-17-0;butyl(triphenyl)phosphanium;chloride;butyl(triphenyl)phosphonium chloride;Phosphonium, butyltriphenyl-, chloride;Phosphonium, butyltriphenyl-, chloride (1:1);Butyltriphenyl phosphonium chloride;EINECS 236-443-3;triphenylbutylphosphonium chloride;butyl(triphenyl)phosphanium chloride;(1-Butyl)triphenylphosphonium chloride;C22H24P.Cl;SCHEMBL159490;C22-H24-P.Cl;DTXSID30884597;Butyl-Triphenyl-Phosphanium Chloride;MFCD00040546;AKOS015915163;B5730;FT-0604872;D89162;A806665;J-006432

Chemical Property of Butyltriphenylphosphonium chloride

Chemical Property:

• Appearance/Colour: white to off-white crystalline powder
• Melting Point: 226-230 °C(lit.)
• Flash Point: >270°C
• PSA: 13.59000
• LogP: 1.78460
• Storage Temp.: Store below +30°C.
• Sensitive.: Hygroscopic
• Solubility.: soluble in Methanol
• Water Solubility.: soluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 354.1304155
• Heavy Atom Count: 24
• Complexity: 273

Purity/Quality:

98%, ^*data from raw suppliers

Butyltriphenylphosphonium Chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xi,Xn
• Statements: 36/37/38-22
• Safety Statements: 26-36-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-]

Technology Process of Butyltriphenylphosphonium chloride

There total 14 articles about Butyltriphenylphosphonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

butylidenetriphenylphosphorane (3728-50-5) + N,N,N',N'-Tetramethylformamidinium chloride (1071-38-1) → tris(dimethylamino)methane (5762-56-1) + butyltriphenylphosphonium chloride (13371-17-0) + <2-(Dimethylamino)-1-propylvinyl>triphenylphosphonium-chlorid (90601-14-2)

Guidance literature:

In tetrahydrofuran; benzene; for 20h;

Reference yield: 88.0%

butylidenetriphenylphosphorane (3728-50-5) + Chlorodifluoromethane (75-45-6) → 1,1-difluoro-1-pentene (4980-66-9) + butyltriphenylphosphonium chloride (13371-17-0) + triphenylphosphine (603-35-0)

Guidance literature:

In various solvent(s); Product distribution; Mechanism;

DOI:10.1021/jo00155a001

Reference yield: 86.7%

n-Butyl chloride (109-69-3) + triphenylphosphine (603-35-0) → butyltriphenylphosphonium chloride (13371-17-0)

Guidance literature:

In acetonitrile; for 10h; Inert atmosphere; Reflux;

upstream raw materials:

carbonochloridic acid, butyl ester

triphenylphosphine

butylidenetriphenylphosphorane

Chlorodifluoromethane

Downstream raw materials:

{(C₆H₅)3PC₄H₉}⁽¹⁺⁾*{FeCl₄}^(1-)={(C₆H₅)3PC₄H₉}{FeCl₄}

(Z)-1-(ortho-pyridyl)-1-pentene

pentylbenzene

(E)-1-phenyl-1-pentene

Refernces

• 1、 El-Harbawi, Mohanad,Yusri, Yasmin Syazwani Bt.,Hossain, M. Ismail. "Toxicity assessment of phosphonium based ionic liquids towards female guppy fish". . p. 2997 - 3000. Retrieved 2014.
• 2、 Santowski, Tobias,Sturm, Alexander G.,Lewis, Kenrick M.,Felder, Thorsten,Holthausen, Max C.,Auner, Norbert. "Synthesis of Functional Monosilanes by Disilane Cleavage with Phosphonium Chlorides". supporting information. p. 3809 - 3815. Retrieved 2019/02/13.
• 3、 -. "One alkyl triphenyl substituted group based phosphonium salt preparation method and application". Paragraph 0054-0061. . Retrieved 2017/09/12.