Dichloro(p-cymene)ruthenium(II) dimer

Base Information

• Chemical Name: Dichloro(p-cymene)ruthenium(II) dimer
• CAS No.: 52462-29-0
• Molecular Formula: C20H28Cl4Ru2
• Molecular Weight: 612.394
• Hs Code.: 28439000
• European Community (EC) Number: 435-530-5,922-316-6,629-445-4
• Wikipedia: (Cymene)ruthenium_dichloride_dimer
• Wikidata: Q4544587
• Mol file: 52462-29-0.mol

Synonyms:Dichloro(p-cymene)ruthenium(II) dimer;52462-29-0;[rucl2(p-cymene)]2;Dichloro(p-cymene)ruthenium(II)dimer;dichlororuthenium;1-methyl-4-propan-2-ylbenzene;(Cymene)ruthenium dichloride dimer;dichloro(p-cymene)ruthenium (II) dimer;Dichloro-(p-cymene)ruthenium(II) dimer;dichloro(p-cymene) ruthenium (II) dimer;dichloro(p-cymene)-ruthenium (II) dimer;Dichloro (p-cymene) ruthenium(II) dimer;Dichloro-(p-cymene)ruthenium (II) dimer;chlororuthenium(1+);dichloride;Di-mu-chlorobis(p-cymene)chlororuthenium(II);Di-mu-chloro-bis[chloro(p-cymene)ruthenium(II)];[Ru(p-cymene)Cl2]2;C20H28Cl4Ru2;(p-Cymene)ruthenium(II) chloride dimer;LAXRNWSASWOFOT-UHFFFAOYSA-J;BCP22504;MFCD00064793;AKOS015903445;BP-12158;Dichloro(p-cymene)ruthenium( cento) dimer;Dichloro(p-cymene)ruthenium(II) dimer, 97%;FT-0624694;Di-?-chlorobis[(p-cymene)chlororuthenium(II)];Di-micro-chlorobis[(p-cymene)chloro-ruthenium];A852732;DI--CHLOROBIS(P-CYMENE)CHLORORUTHENIUM(II);Di-mu-chloro-bis[chloro(p-cymene)ruthenium[ cento];J-400837;Q4544587;Di-I(1/4)-chlorobis[(p-cymene)chlororuthenium(II)];Di-mu-chloro-bis[chloro(p-cymene)ruthenium[ inverted exclamation marke degrees ]

Chemical Property of Dichloro(p-cymene)ruthenium(II) dimer

Chemical Property:

• Appearance/Colour: red-orange to red-brown crystals or powder
• Melting Point: 247.0-250.0 °C (dec.)(lit.)
• Boiling Point: 173.9oC at 760mmHg
• Flash Point: 47.2oC
• PSA: 0.00000
• LogP: 8.99480
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: Chloroform (Sparingly), Ethyl Acetate (Sparingly)
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 615.90133
• Heavy Atom Count: 26
• Complexity: 89

Purity/Quality:

98%, ^*data from raw suppliers

Dichloro(p-cymene)ruthenium(II) Dimer ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22-36-52/53
• Safety Statements: 26-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)C(C)C.CC1=CC=C(C=C1)C(C)C.Cl[Ru]Cl.Cl[Ru]Cl
• Uses: Hydrosilylation Catalysts Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation Dichloro(p-cymene)ruthenium(II) dimer is used as hydrosilylation catalyst and also used as a pharmaceutical intermediate.

Technology Process of Dichloro(p-cymene)ruthenium(II) dimer

There total 35 articles about Dichloro(p-cymene)ruthenium(II) dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

rhodium(III) chloride hydrate + (R)-5-isopropyl-2-methylcyclohexa-1,3-diene (4221-98-1) → [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0)

Guidance literature:

In methanol; at 140 ℃; for 0.166667h; Microwave irradiation;

DOI:10.3390/molecules26040939

Reference yield: 98.0%

p-mentha-1,5-diene (99-83-2) + rhodium(III) chloride hydrate → [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0)

Guidance literature:

In ethanol; for 17h; Schlenk technique; Reflux; Inert atmosphere;

DOI:10.1016/j.jorganchem.2018.05.020

Reference yield: 98.0%

4-methylisopropylbenzene (99-87-6) + ruthenium(III) chloride hydrate → [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0)

Guidance literature:

In 2-methoxy-ethanol; water; at 120 ℃; for 4h; Product distribution / selectivity;

upstream raw materials:

Ru(η6-p.cymene)(η4-cycloocta-1,5-diene)

ruthenium trichloride

p-mentha-1,5-diene

ruthenium trichloride hydrate

Refernces

• 1、 Queyriaux, Nicolas,Giannoudis, Emmanouil,Lefebvre, Jean-Fran?ois,Artero, Vincent,Chavarot-Kerlidou, Murielle. "Synthesis of Ruthenium Tris-Diimine Photosensitizers Substituted by Four Methylphosphonate Anchoring Groups for Dye-Sensitized Photoelectrochemical Cell Applications". . p. 2154 - 2161. Retrieved 2019.
• 2、 Abhijna Krishna, Ramakrishnan,Dheepika, Ramachandran,Muralisankar, Mathiyan,Nagarajan, Samuthira. "Microwave-assisted synthesis and DNA-binding studies of half-sandwich ruthenium(II) arene complexes containing phenanthroimidazole-triarylamine hybrids". . p. 838 - 849. Retrieved 2021.
• 3、 Chakraborty, Debjani,Dash, Soumya R.,Devkar, Ranjitsinh,Khanvilkar, Priyanka,Pulipaka, Ramadevi,Shirsath, Kavita. "Imidazole/4,4′-azopyridine bridging binuclear Ru(II) complexes: design, synthesis, bimolecular interactions and cytotoxicity against HeLa cell line". . p. 3313 - 3326. Retrieved 2021.
• 4、 Audi Fong,Andy Hor,Henderson, William,Nicholson, Brian K.,Gardyne, Stephen,Devoy, Sarah M.. "Coordination chemistry of the [Pt2(μ-S)2 (PPh3)4] metalloligand with π-hydrocarbon derivatives of d6 ruthenium(II), osmium(II), rhodium(III) and iridium(III)". . p. 24 - 31. Retrieved 2003.
• 5、 Khanvilkar, Priyanka,Pulipaka, Ramadevi,Shirsath, Kavita,Devkar, Ranjitsinh,Chakraborty, Debjani. "Organometallic binuclear Ru(II) complexes: Design, synthesis, DNA/BSA binding interactions and in-vitro cytotoxicity against HeLa cell line". . p. 134 - 140. Retrieved 2019.
• 6、 Fandzloch, Marzena,J?drzejewski, Tomasz,Dobrzańska, Liliana,Esteban-Parra, Ginés M.,Wi?niewska, Joanna,Paneth, Agata,Paneth, Piotr,Sitkowski, Jerzy. "New organometallic ruthenium(ii) complexes with purine analogs - a wide perspective on their biological application". . p. 5557 - 5573. Retrieved 2021.
• 7、 Suravajjala, Sandhya,Polam, Jayapal Reddy,Porter, Leigh Christopher. "Bis(arene) complexes of RuII. Synthesis, crystal structure and electrochemical behavior of 6-p-isopropyltoluene)Ru>2". . p. 201 - 206. Retrieved 1993.
• 8、 Joseph, M. C.,Mapolie, S. F.,Swarts, A. J.. "Cationic half-sandwich ruthenium (II) complexes ligated by pyridyl-triazole ligands: Transfer hydrogenation and mechanistic studies". supporting information. . Retrieved 2021/11/30.