Phenyltriallylsilane

Base Information

• Chemical Name: Phenyltriallylsilane
• CAS No.: 2633-57-0
• Molecular Formula: C15H20Si
• Molecular Weight: 228.409
• Hs Code.: 29310099
• European Community (EC) Number: 833-840-9
• DSSTox Substance ID: DTXSID50369795
• Nikkaji Number: J944.850K
• Wikidata: Q82157104
• Mol file: 2633-57-0.mol

Synonyms:PHENYLTRIALLYLSILANE;2633-57-0;triallyl(phenyl)silane;phenyl-tris(prop-2-enyl)silane;Benzene,(tri-2-propen-1-ylsilyl)-;triallylphenylsilane;phenyl-triallyl-silane;DTXSID50369795;phenyltris(prop-2-en-1-yl)silane;Triallyl(phenyl)silane, >/=95%;CAA63357;MFCD00094138;Benzene, (tri-2-propen-1-ylsilyl)-;BS-22165;FT-0634415;T3550;T72192

Chemical Property of Phenyltriallylsilane

Chemical Property:

• Appearance/Colour: colorless liquid
• Vapor Pressure: 0.00276mmHg at 25°C
• Refractive Index: 1.501
• Boiling Point: 295 °C at 760 mmHg
• Flash Point: 118.1 °C
• PSA: 0.00000
• Density: 0.88 g/cm³
• LogP: 3.90040
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 228.133427172
• Heavy Atom Count: 16
• Complexity: 209

Purity/Quality:

98%min ^*data from raw suppliers

Triallyl(phenyl)silane >95.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 48-23/24/25
• Safety Statements: 45-38-36/37/39-28A

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC[Si](CC=C)(CC=C)C1=CC=CC=C1

Technology Process of Phenyltriallylsilane

There total 6 articles about Phenyltriallylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

Phenyltrichlorosilane (98-13-5) + allylsamarium bromide (346713-20-0) → triallyl(phenyl)silane (2633-57-0)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1016/j.jorganchem.2006.07.023

Reference yield: 96.49%

allylmagnesium bromide (2622-05-1) + Phenyltrichlorosilane (98-13-5) → triallyl(phenyl)silane (2633-57-0)

Guidance literature:

In tetrahydrofuran; at -0.16 - 4.84 ℃; for 24h;

DOI:10.1039/c3ra00023k

Reference yield: 96.0%

Phenyltrichlorosilane (98-13-5) + allylmagnesium bromide (1730-25-2) → triallyl(phenyl)silane (2633-57-0)

Guidance literature:

In diethyl ether; at 20 ℃;

DOI:10.1002/ejic.200500182

upstream raw materials:

Phenyltrichlorosilane

allylmagnesium bromide

allylmagnesium bromide

allylsamarium bromide

Downstream raw materials:

tris[3-(triallylsilyl)propyl]phenylsilane

biphenyl-4-acetaldehyde

1-phenyl-4-nitrobenzene

4-fluoro-biphenyl

Refernces

• 1、 Zhang, Daohong,Liang, Enbin,Li, Tingcheng,Chen, Sufang,Zhang, Junheng,Cheng, Xinjian,Zhou, Jiliang,Zhang, Aiqing. "The effect of molecular weight of hyperbranched epoxy resins with a silicone skeleton on performance". . p. 9522 - 9529. Retrieved 2013.
• 2、 Li, Zhifang,Cao, Xiaojun,Lai, Guoqiao,Liu, Jinhua,Ni, Yong,Wu, Jirong,Qiu, Huayu. "Controlled introduction of allylic group to chlorosilanes". . p. 4740 - 4746. Retrieved 2007/10/03.