cis-Dichlorobis(diethylsulfide)platinum(II)

Base Information

• Chemical Name: cis-Dichlorobis(diethylsulfide)platinum(II)
• CAS No.: 14873-92-8
• Deprecated CAS: 62346-77-4
• Molecular Formula: C8H20 Cl2 Pt S2
• Molecular Weight: 446.365
• European Community (EC) Number: 239-454-1,238-944-2,239-373-1
• Mol file: 14873-92-8.mol

Synonyms:15442-57-6;cis-Dichlorobis(diethylsulfide)platinum(II);cis-Dichlorobis(diethyl sulfide)platinum(II);14873-92-8;EINECS 238-944-2;trans-Dichlorobis(diethylsulfide)platinum(II);dichloroplatinum;ethylsulfanylethane;C8H20Cl2PtS2;MFCD00050943;NSC 137445;Dichlorobis(1,1'-thiobis(ethane))platinum;dichlorobis[1,1/'-thiobis[ethane]]platinum;Platinum, dichlorobis(1,1'-thiobis(ethane))-;Platinum, dichlorobis[1,1'-thiobis[ethane]]-;C8-H20-Cl2-Pt-S2;trans-Dichlorobis(diethylsulfide)platinum(II), Pt 43.7%;Dichlorobis[1,1'-thiobis[ethane]]platinum;DICHLOROPLATINUM, ETHYLSULFANYLETHANE;cis-Bis(diethyl sulfide)platinum(II) chloride;SCHEMBL1238515;Platinum, dichlorobis(ethyl sulfide)-;AKOS015964362;SC10697;[Pt](Cl)(Cl)(S(CC)CC)S(CC)CC;AC-18108;cis-dichlorobis(diethylsulfide) platinum (ii);E80909;CIS-DICHLOROBIS(1,1'-THIOBISETHANE)PLATINUM;CIS-BIS(DIETHYL SULFIDE)PLATINUM(II) CHLORIDE;CIS-DICHLOROBIS(DIETHYLSULFIDE)PLATINUM(II);DICHLOROBIS(DIETHYLSULPHIDE)PLATINATE (II);TRANS-DICHLOROBIS(DIETHYLSULFIDE)PLATINUM(II)

Chemical Property of cis-Dichlorobis(diethylsulfide)platinum(II)

Chemical Property:

• Vapor Pressure: 54.2mmHg at 25°C
• Boiling Point: 94.4°Cat760mmHg
• Flash Point: °C
• PSA: 50.60000
• Density: g/cm³
• LogP: -2.47570
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 445.003143
• Heavy Atom Count: 13
• Complexity: 13.9

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCSCC.CCSCC.Cl[Pt]Cl

Technology Process of cis-Dichlorobis(diethylsulfide)platinum(II)

There total 32 articles about cis-Dichlorobis(diethylsulfide)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

diethyl sulphide (352-93-2) + platinum(II) chloride (10025-65-7) → dichlorobis(diethyl sulfide)platinum (14873-92-8)

Guidance literature:

In benzene; N2-atmosphere; excess of Et2S; filtration, filtrate evapn. (vac.);

Reference yield: 92.0%

ammonium hexachloroplatinate + diethyl sulphide (352-93-2) → dichlorobis(diethyl sulfide)platinum (14873-92-8)

Guidance literature:

With Na₂SO₃; In water; addn. of excess Et2S to Pt-complex suspn., stirring (room temp., 30 min), heating to 80°C, slow addn. of Na2SO3 soln., stirring (room temp., 1 h); addn. of concd. HCl, boiling for 30 min, solvent removal, extn. into CH2Cl2, drying (MgSO4), solvent removal, pptn. on Et2O addn., drying (vac.); isomer mixt. (cis:trans=2:1) not sepd.; elem. anal.;

DOI:10.1016/S0022-328X(98)00761-X

Reference yield: 83.0%

potassium tetrachloroplatinate(II) (10025-99-7) + diethyl sulphide (352-93-2) → cis-dichlorobis(diethylsulfide)platinum(II) (14873-92-8,20244-83-1,15337-84-5,15442-57-6) + trans-dichlorobis(diethyl sulfide)platinum(II) (14873-92-8,20244-83-1,15442-57-6,15337-84-5)

Guidance literature:

In water; byproducts: KCl; (inert atm.); addn. of diethylsulfide to aq. soln. of platinum compd., stirring for 24 h; evapn. at 25°C in vac., extn. (hot benzene), filtration, concg., cooling to 0°C, filtration, washing with hexane, NMR;

DOI:10.1021/om700997v

upstream raw materials:

diethyl sulphide

platinum(II) chloride

trans-dichloro(ethylene)(phenazine)platinum

trans-dichlorobis(diethyl sulfide)platinum(II)

Downstream raw materials:

(CH₃Si(C₆H₄P(C₆H₁₁)2)2)PtCl

trans-(Et2SPtCl2PPh2(η5-C5H4))Fe(η5-C5H4C5H2N(C5H4N)2)

tris(triphenylphosphine)platinum⁽⁰⁾

{PtBr2}

Refernces

• 1、 Rashidi, Mehdi,Esmaeilbeig, Ahmad R.,Shahabadi, Nahid,Tangestaninejad, Shahram,Puddephatt, Richard J.. "Some mono- and binuclear platinacyclopentane complexes: A comparative kinetic study of reaction of ethyl iodide with platina(II)cyclopentane and dimethylplatinum(II) complexes". . p. 53 - 61. Retrieved 1998.
• 2、 Fekl, Ulrich,Zahl, Achim,Van Eldik, Rudi. "Detailed mechanistic information on methane elimination from a methyl(hydrido)platinum(IV) complex. Relevance for the mechanism of methane activation". . p. 4156 - 4164. Retrieved 1999.
• 3、 De Crisci, Antonio G.,Lough, Alan J.,Multani, Kanwarpal,Fekl, Ulrich. "9,10-dihydroplatinaanthracenes with aromatic diimine ligands: Syntheses and spectroscopic and computational studies of new luminescent materials". . p. 1765 - 1779. Retrieved 2009/02/01.