1,1,1,2,3,4,4,5,5,6,6,6-Dodecafluorohex-2-ene

Base Information

• Chemical Name: 1,1,1,2,3,4,4,5,5,6,6,6-Dodecafluorohex-2-ene
• CAS No.: 1584-00-5
• Molecular Formula: C6F12
• Molecular Weight: 300.047
• Hs Code.: 2903399090
• DSSTox Substance ID: DTXSID80402088
• Mol file: 1584-00-5.mol

Synonyms:perfluoro-2-hexene;1,1,1,2,3,4,4,5,5,6,6,6-dodecafluorohex-2-ene;(E)-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluorohex-2-ene;SCHEMBL321309;DTXSID80402088;JBDBBTPNNYKSQX-UHFFFAOYSA-N;FT-0676889

Chemical Property of 1,1,1,2,3,4,4,5,5,6,6,6-Dodecafluorohex-2-ene

Chemical Property:

• Vapor Pressure: 183mmHg at 25°C
• Refractive Index: 1.268
• Boiling Point: 63.5°Cat760mmHg
• Flash Point: 2°C
• PSA: 0.00000
• Density: 1.61g/cm³
• LogP: 4.53220
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 2
• Exact Mass: 299.9808379
• Heavy Atom Count: 18
• Complexity: 341

Purity/Quality:

98%min ^*data from raw suppliers

Perfluorohexene-2 ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=C(C(F)(F)F)F)(C(C(C(F)(F)F)(F)F)(F)F)F

Technology Process of 1,1,1,2,3,4,4,5,5,6,6,6-Dodecafluorohex-2-ene

There total 2 articles about 1,1,1,2,3,4,4,5,5,6,6,6-Dodecafluorohex-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-perfluorohexyl iodide (355-43-1) → 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorohexane (355-37-3) + perfluoro-1-hexene (755-25-9) + perfluoro-3-hexene (1584-02-7) + dodecafluoro-hex-2-ene (1584-00-5)

Guidance literature:

With copper; zinc; methyl iodide; In dimethyl sulfoxide; at 20 ℃; Product distribution; further organic halides as reaction partners;

DOI:10.1016/S0022-1139(00)82214-9

Reference yield:

perfluoroheptanoic acid sodium salt (20109-59-5) → dodecafluoro-hex-2-ene (1584-00-5)

Guidance literature:

(pyrolysis);

Reference yield:

dodecafluoro-hex-2-ene (1584-00-5) → Fluorosulfuric acid 1,2,3,3,4,4,5,5,5-nonafluoro-2-fluorosulfonyloxy-1-trifluoromethyl-pentyl ester (75677-97-3) + 2,3-Dichloro-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-hexane + Fluorosulfuric acid 1-(1-chloro-1,2,2,2-tetrafluoro-ethyl)-1,2,2,3,3,4,4,4-octafluoro-butyl ester (83654-36-8) + Fluorosulfuric acid 2-chloro-1,2,3,3,4,4,5,5,5-nonafluoro-1-trifluoromethyl-pentyl ester (83654-37-9)

Guidance literature:

With sodium fluorosulfonate; fluorosulphonic acid; chlorine; for 3h; Title compound not separated from byproducts; electrolysis;

DOI:10.1007/BF01150910

upstream raw materials:

perfluoroheptanoic acid sodium salt

n-perfluorohexyl iodide

Downstream raw materials:

Fluorosulfuric acid 1,2,3,3,4,4,5,5,5-nonafluoro-2-fluorosulfonyloxy-1-trifluoromethyl-pentyl ester

Fluorosulfuric acid 1-(1-chloro-1,2,2,2-tetrafluoro-ethyl)-1,2,2,3,3,4,4,4-octafluoro-butyl ester

Fluorosulfuric acid 2-chloro-1,2,3,3,4,4,5,5,5-nonafluoro-1-trifluoromethyl-pentyl ester

Refernces