Perfluorohex-1-ene

Base Information

• Chemical Name: Perfluorohex-1-ene
• CAS No.: 755-25-9
• Molecular Formula: C6F12
• Molecular Weight: 300.047
• Hs Code.: 2903590090
• European Community (EC) Number: 212-047-6
• DSSTox Substance ID: DTXSID00226440
• Nikkaji Number: J95.345H
• Mol file: 755-25-9.mol

Synonyms:Perfluorohex-1-ene;perfluorohexene-1;755-25-9;1,1,2,3,3,4,4,5,5,6,6,6-dodecafluorohex-1-ene;EINECS 212-047-6;perfluorohexene;perfluoro-1-hexene;SCHEMBL59848;DTXSID00226440;MFCD04038339;AKOS016015487;FT-0676888;A838444;1,1,2,3,3,4,4,5,5,6,6,6-dodecafluoro-1-hexene;1-Hexene, 1,1,2,3,3,4,4,5,5,6,6,6-dodecafluoro-;1,1,2,3,3,4,4,5,5,6,6,6-dodecakis(fluoranyl)hex-1-ene

Chemical Property of Perfluorohex-1-ene

Chemical Property:

• Vapor Pressure: 218mmHg at 25°C
• Melting Point: 57 °C
• Refractive Index: 1.2584 (estimate)
• Boiling Point: 57°C
• Flash Point: 0°C
• PSA: 0.00000
• Density: 1.61g/cm³
• LogP: 4.53220
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 3
• Exact Mass: 299.9808379
• Heavy Atom Count: 18
• Complexity: 342

Purity/Quality:

98%Min ^*data from raw suppliers

Perfluorohexene-1 ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=C(F)F)(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)F

Technology Process of Perfluorohex-1-ene

There total 7 articles about Perfluorohex-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.13%

→ perfluoro-1-hexene (755-25-9)

Guidance literature:

With sodium butanolate; In butan-1-ol; at 50 ℃;

Reference yield: 1.0%

xenon difluoride (13709-36-9) + perfluoro-trans-hex-1-enyldifluoroborane (375856-42-1) → perfluorohexyldifluoroborane (329009-01-0) + trans-1H-perfluorohexene (391199-64-7) + tetradecafluorohexane (355-42-0) + perfluoro-1-hexene (755-25-9)

Guidance literature:

In further solvent(s); solid XeF2 added in small portions to a cold (-30°C) stirred soln. of trans-C4F9CF=CFBF2 in 1,1,1,3,3-perfluorobutane; soln. stirred at -30°C for 1 h and then kept for 30 min without stirring; not isolated; detected by (19)F-NMR;

DOI:10.1002/zaac.200300234

Reference yield:

perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) + Phenyl glycidyl ether (122-60-1,71031-02-2) → 1,1,1,2,3,3,3-Heptafluoropropane (431-89-0) + perfluoro-1-hexene (755-25-9) + 1,1,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-Octadecafluoro-1-nonene (376-22-7) + perfluoropropenyl phenyl ether (2338-68-3) + perfluorohexenyl phenyl ether + perfluorododecene (1828-40-6)

Guidance literature:

potassium hydrogen bifluoride; In acetonitrile; at 80 ℃; for 1h; Product distribution; other polyfluoro olefins, other catalysts;

upstream raw materials:

perfluoroheptanoic acid sodium salt

perfluoropropylene

Phenyl glycidyl ether

n-perfluorohexyl iodide

Downstream raw materials:

tetradecafluorohexane

perfluoro-2-pentenoyl fluoride phenylhydrazone

2-hydroperfluorocaproyl fluoride phenylhydrazone

C₁₂H₆F₁₀N₂

Refernces

• 1、 Frohn, Hermann-Josef,Adonin, Nicolay Yu.,Bardin, Vadim V.. "The Reaction of 2-X-1,2-Difluoroalk-1-enyldifluoroboranes with Xenon Difluoride. A Methodical Approach to 1,2-Difluoroalk-1-enylxenon(II) Salts". . p. 2499 - 2508. Retrieved 2008/10/09.
• 2、 Solov'ev, D. V.,Dokuchaev, P. Yu.,Rodin, A. A.,Mushenko, V. D.,Kavrent'ev, A. N.. "REACTIVITY OF FLUOROOLEFINS IN REACTIONS WITH OXIRANES UNDER BASE CATALYSIS CONDITIONS". . p. 76 - 84. Retrieved 2007/10/02.