2-CHLOROETHYLPHOSPHORIC ACID DICHLORIDE

Base Information

• Chemical Name: 2-CHLOROETHYLPHOSPHORIC ACID DICHLORIDE
• CAS No.: 1455-05-6
• Molecular Formula: C2H4 Cl3 O2 P
• Molecular Weight: 197.385
• Mol file: 1455-05-6.mol

Synonyms:Ethanol,2-chloro-, phosphorodichloridate (8CI); 2-Chloroethyl dichlorophosphate;2-Chloroethyl phosphoric dichloride; 2-Chloroethyl phosphorodichloridate; b-Chloroethyl dichlorophosphate; b-Chloroethylphosphorodichloridate

Chemical Property of 2-CHLOROETHYLPHOSPHORIC ACID DICHLORIDE

Chemical Property:

• Vapor Pressure: 0.0377mmHg at 25°C
• Refractive Index: 1.458
• Boiling Point: 100 °C / 20mmHg
• Flash Point: 107.7°C
• PSA: 36.11000
• Density: 1,55 g/cm3
• LogP: 2.82750
• Storage Temp.: Hygroscopic, Refrigerator, under inert atmosphere
• Solubility.: Chloroform (Sparingly)

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Chloroethylphosphoryl Dichloride ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-CHLOROETHYLPHOSPHORIC ACID DICHLORIDE

There total 13 articles about 2-CHLOROETHYLPHOSPHORIC ACID DICHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-chloro-ethanol (107-07-3) → 2-chloroethyl phosphorodichloridate (1455-05-6) + bis(2-chloroethyl) chlorophosphate (6087-94-1)

Guidance literature:

With trichlorophosphate; unter Eiskuehlung, dann bei 140grad;

Reference yield:

2-chloro-ethanol (107-07-3) + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3) → 2-chloroethyl phosphorodichloridate (1455-05-6) + bis(2-chloroethyl) chlorophosphate (6087-94-1)

Guidance literature:

Reference yield:

2-ethyl 2-chloroethyl (2-chloroethyl)phosphonate → 2-chloroethyl phosphorodichloridate (1455-05-6) + 1,2-dichloro-ethane (107-06-2,52399-93-6)

Guidance literature:

With phosphorus pentachloride; Product distribution; various temperatures;

upstream raw materials:

oxirane

2-chloro-1,3,2-dioxaphospholan

2-chloro-ethanol

phenylphosphonothioic-di(2-chloroethyl)ester

Downstream raw materials:

bis-aziridin-1-yl-phosphinic acid-(2-chloro-ethyl ester)

2-chloroethyl diethyl phosphate

phosphoric acid-(2-chloro-ethyl ester)-bis-(4-nitro-phenyl ester)

2-chloroethyl phosphoric acid

Refernces

• 1、 Tang, Chu Chi,Wu, Gui Ping,Huang, Guang Yan,Li, Zhen,Jin, Gui Yu. "THE ISOMERIZATION/CHLORINATION OF O,O-DIALKYL PHENYLTHIOPHOSPHONATES WITH PHOSPHORUS OXYCHLORIDE - A NEW CONVENIENT SYNTHESIS OF S-ALKYL PHENYLTHIOPHOSPHONIC ACID DERIVATIVES". . p. 159 - 164. Retrieved 2007/10/02.
• 2、 Blinova, G. G.,Zhukova, I. L.,Lavrent'ev, A. N.,Mel'nikova, L. N.. "BY-PRODUCT IN THE PREPARATION OF TRIS-2-CHLOROETHYL PHOSPHITE AND OF ITS ISOMERIZATION INTO A PHOSPHONATE". . p. 2467 - 2468. Retrieved 2007/10/02.