PROPENE-2-D1

Base Information

• Chemical Name: PROPENE-2-D1
• CAS No.: 1184-59-4
• Molecular Formula: C3H5D
• Molecular Weight: 43.0727
• Mol file: 1184-59-4.mol

Synonyms:PROPENE-2-D1;Propene-2-D1 (gas)

Chemical Property of PROPENE-2-D1

Chemical Property:

• PSA: 0.00000
• LogP: 1.19230

Purity/Quality:

98%,99%, ^*data from raw suppliers

Propene-2-d1(gas) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of PROPENE-2-D1

There total 8 articles about PROPENE-2-D1 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → (Z)-propene-1-d1 (1117-90-4,1560-60-7) + trans-propene-d1 (1117-91-5,1560-60-7) + 3-deuteriopropene (1117-89-1) + propene-2-d1 (1184-59-4)

Guidance literature:

With deuterium; palladium; at -63.1 ℃; Product distribution; Mechanism; also other catalysts ( Ni, Pt, Ni-Cu, Pd-Cu, Pt-Cu, Cu) and reaction conditions (180 - 263 K);

DOI:10.1039/c39870000363

Reference yield:

1,1,1-trichloroethane (71-55-6,74552-83-3) → dimethylacetylene (503-17-3) + 1-deuterio-acetaldehyde (4122-13-8) + 1,1,1-trideuterio-ethane (2031-95-0) + ethylene-1,1-d2 (6755-54-0) + d1-vinyl chloride (4984-12-7) + propene-2-d1 (1184-59-4) + C4H5(2)H (138815-21-1)

Guidance literature:

With chromium(II) perchlorate; water-d2; at 20 ℃; for 0.333333h;

DOI:10.1002/chem.201202918

Reference yield:

5,5-dideuterio-hexan-2-one (24300-67-2) → propene-2-d1 (1184-59-4) + acetone-d1 (4468-52-4) + acetone (67-64-1)

Guidance literature:

at 27 ℃; under 7 Torr; in der Dampfphase durch gefiltertes Licht (lambda: 313nm).Photolysis;

DOI:10.1021/ja01528a013

upstream raw materials:

5,5-dideuterio-hexan-2-one

propene

hexadeuteriopropene

1-iodopropane-2,2-d₂

Downstream raw materials:

((Ph3P)2Ir(2)H(π-allyl))3PW12O40

((Ph3P)2Ir(H)(π-allyl))3PW12O40

((Ph₃P)2Ir(D)H)3PW₁₂O₄₀

(Z)-propene-1-d1

Refernces

• 1、 Levy, Ophir,Bino, Avi. "Metal ions do not play a direct role in the formation of carbon-carbon triple bonds during reduction of trihaloalkyls by CrII or V II". supporting information. p. 15944 - 15947. Retrieved 2013/02/23.
• 2、 Naito, Shuichi,Tanimoto, Mitsutoshi. "Novel Support Effects on the Mechanism of Propene-Deuterium Addition and Exchange Reactions over Dispersed ZrO2". . p. 306 - 313. Retrieved 2007/10/03.