cis-Dichlorobis(diethylsulfide)platinum(II)

Base Information

• Chemical Name: cis-Dichlorobis(diethylsulfide)platinum(II)
• CAS No.: 15337-84-5
• Deprecated CAS: 62346-77-4
• Molecular Formula: C₈H₂₀Cl₂PtS₂
• Molecular Weight: 446.365
• European Community (EC) Number: 239-454-1,238-944-2,239-373-1
• Mol file: 15337-84-5.mol

Synonyms:15442-57-6;cis-Dichlorobis(diethylsulfide)platinum(II);cis-Dichlorobis(diethyl sulfide)platinum(II);14873-92-8;EINECS 238-944-2;trans-Dichlorobis(diethylsulfide)platinum(II);dichloroplatinum;ethylsulfanylethane;C8H20Cl2PtS2;MFCD00050943;NSC 137445;Dichlorobis(1,1'-thiobis(ethane))platinum;dichlorobis[1,1/'-thiobis[ethane]]platinum;Platinum, dichlorobis(1,1'-thiobis(ethane))-;Platinum, dichlorobis[1,1'-thiobis[ethane]]-;C8-H20-Cl2-Pt-S2;trans-Dichlorobis(diethylsulfide)platinum(II), Pt 43.7%;Dichlorobis[1,1'-thiobis[ethane]]platinum;DICHLOROPLATINUM, ETHYLSULFANYLETHANE;cis-Bis(diethyl sulfide)platinum(II) chloride;SCHEMBL1238515;Platinum, dichlorobis(ethyl sulfide)-;AKOS015964362;SC10697;[Pt](Cl)(Cl)(S(CC)CC)S(CC)CC;AC-18108;cis-dichlorobis(diethylsulfide) platinum (ii);E80909;CIS-DICHLOROBIS(1,1'-THIOBISETHANE)PLATINUM;CIS-BIS(DIETHYL SULFIDE)PLATINUM(II) CHLORIDE;CIS-DICHLOROBIS(DIETHYLSULFIDE)PLATINUM(II);DICHLOROBIS(DIETHYLSULPHIDE)PLATINATE (II);TRANS-DICHLOROBIS(DIETHYLSULFIDE)PLATINUM(II)

Chemical Property of cis-Dichlorobis(diethylsulfide)platinum(II)

Chemical Property:

• Melting Point: 105 °C(lit.)
• Boiling Point: 94.4 °C at 760 mmHg
• Flash Point: °C
• PSA: 77.60000
• Density: g/cm³
• LogP: 4.35990
• Solubility.: Soluble in acetone, alcohol, ethyl acetate and benzene
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 445.003143
• Heavy Atom Count: 13
• Complexity: 13.9

Purity/Quality:

99% ^*data from raw suppliers

TRANS-DICHLOROBIS(DIETHYLSULFIDE)PLATINUM(II) 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCSCC.CCSCC.Cl[Pt]Cl
• Uses: It is used in Hydrosilylation. Platinum(II) complexes of diethylsulfide are convenient and versatile precursor for the preparation of a variety of organoplatinum(II) derivatives.

Technology Process of cis-Dichlorobis(diethylsulfide)platinum(II)

There total 27 articles about cis-Dichlorobis(diethylsulfide)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

potassium tetrachloroplatinate(II) (10025-99-7) + diethyl sulphide (352-93-2) → cis-dichlorobis(diethylsulfide)platinum(II) (14873-92-8,20244-83-1,15337-84-5,15442-57-6) + trans-dichlorobis(diethyl sulfide)platinum(II) (14873-92-8,20244-83-1,15442-57-6,15337-84-5)

Guidance literature:

In water; byproducts: KCl; (inert atm.); addn. of diethylsulfide to aq. soln. of platinum compd., stirring for 24 h; evapn. at 25°C in vac., extn. (hot benzene), filtration, concg., cooling to 0°C, filtration, washing with hexane, NMR;

DOI:10.1021/om700997v

Reference yield: 83.0%

potassium tetrachloroplatinate(II) (10025-99-7) + diethyl sulphide (352-93-2) → cis-dichlorobis(diethylsulfide)platinum(II) (14873-92-8,20244-83-1,15337-84-5,15442-57-6) + trans-dichlorobis(diethyl sulfide)platinum(II) (14873-92-8,20244-83-1,15442-57-6,15337-84-5)

Guidance literature:

In water; byproducts: KCl; (inert atm.); addn. of diethylsulfide to aq. soln. of platinum compd., stirring for 24 h; evapn. at 25°C in vac., extn. (hot benzene), filtration, concg., cooling to 0°C, filtration, washing with hexane, NMR;

DOI:10.1021/om700997v

Reference yield:

{Pt2} (148832-26-2) → cis-dichlorobis(diethylsulfide)platinum(II) (14873-92-8,20244-83-1,15337-84-5,15442-57-6)

Guidance literature:

Multi-step reaction with 3 steps

1: water

2: water

3: hydrogenchloride

In hydrogenchloride; water;

DOI:10.1039/JR9300000349

upstream raw materials:

trans-dichlorobis(diethyl sulfide)platinum(II)

diethyl sulphide

potassium tetrachloroplatinate(II)

hydrogenchloride

Downstream raw materials:

{PtBr2}

trans-dichlorobis(diethyl sulfide)platinum(II)

cis-dichlorobis(diethylsulfide)platinum(II)

{Ptaes₂Cl₄}

Refernces

• 1、 Hansson, Christian. "Cis-Dichloridobis(diethyl sulfide-κS)platinum(II) at 295 and 150 K". . p. m361-m363. Retrieved 2008/09/16.
• 2、 Tobita, Hiromi,Habazaki, Hiroki,Ogino, Hiroshi. "Fast Cis-Trans Isomerization of Square-Planar Bis(diethyl sulfide)platinum(II) Complexes. Reaction of cis-Dichlorobis(diethyl sulfide)platinum(II) with Mesityllithium". . p. 797 - 799. Retrieved 2007/10/02.