1-AZIDOADAMANTANE 97

Base Information

• Chemical Name: 1-AZIDOADAMANTANE 97
• CAS No.: 24886-73-5
• Molecular Formula: C10H15 N3
• Molecular Weight: 177.249
• Hs Code.: 2929909090
• Mol file: 24886-73-5.mol

Synonyms:Adamantane,1-azido- (8CI); 1-Adamantyl azide; 1-Azidoadamantane; Adamantan-1-yl azide; NSC614999

Chemical Property of 1-AZIDOADAMANTANE 97

Chemical Property:

• Melting Point: 80-82 °C(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 49.75000
• Density: g/cm³
• LogP: 2.71826

Purity/Quality:

99% ^*data from raw suppliers

1-Azidoadamantane 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F
• Statements: 11
• Safety Statements: 16-33

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-AZIDOADAMANTANE 97

There total 4 articles about 1-AZIDOADAMANTANE 97 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

methyl 1-adamantylcarbonyloxy(phenyl)carbamodithioate (1013632-22-8) → 1-Azidoadamantane (24886-73-5) + 1-adamantyl methyl phenylcarbonimidodithioate (1013632-26-2)

Guidance literature:

With phenylsulfonyl azide; In dichloromethane; at 5 ℃; for 4h; Sunlight irradiation;

DOI:10.1021/ol702832x

Reference yield: 4.9%

adamantane (281-23-2) → 2-Adamantanone (700-58-3) + 1-Azidoadamantane (24886-73-5) + 1-adamanthanol (768-95-6) + 1-azidoadamantane (34197-88-1)

Guidance literature:

With tert.-butylhydroperoxide; sodium azide; ferric nitrate; In pyridine; acetic acid; at 60 ℃; for 11h; Further byproducts given;

DOI:10.1016/S0040-4020(01)80736-5

Reference yield: 4.9%

pyridine (110-86-1) + adamantane (281-23-2) → 2-Adamantanone (700-58-3) + 2-(adamantan-1-yl)pyridine + 1-Azidoadamantane (24886-73-5) + 1-adamanthanol (768-95-6)

Guidance literature:

With tert.-butylhydroperoxide; sodium azide; ferric nitrate; In acetic acid; at 60 ℃; for 11h; Further byproducts given;

DOI:10.1016/S0040-4020(01)80736-5

upstream raw materials:

pyridine

adamantane

methyl 1-adamantylcarbonyloxy(phenyl)carbamodithioate

Downstream raw materials:

1-(adamantan-1-yl)-4-phenyl-1H-[1,2,3]-triazole

1-(1-adamantyl)-5-phenyl-1H-1,2,3-triazole

6-hydroxy-5-azatricyclo<4.3.1.1^3,8>undecane

3-Cyano-4-azahomoadamantane

Refernces

• 1、 Barton, Derek H. R.,Warinthorn, Chavasiri. "The Functionalization of Saturated Hydrocarbons. Part 26. Ionic Substitution Reactions in GoAggIV Chemistry: The Construction of C-N, C-S and C-C Bonds". . p. 47 - 60. Retrieved 2007/10/02.