Triiodide Ion

Base Information

• Chemical Name: Triiodide Ion
• CAS No.: 14900-04-0
• Deprecated CAS: 721396-52-7,58238-87-2,63443-32-3,65219-61-6,65436-42-2,68277-87-2,78414-31-0,91117-61-2,43732-74-7
• Molecular Formula: I₃
• Molecular Weight: 380.714
• UNII: DA1N05631Q
• DSSTox Substance ID: DTXSID40164150
• Wikipedia: Triiodide,Triiodide ion
• Wikidata: Q1446811
• Mol file: 14900-04-0.mol

Synonyms:Triiodide Ion;Periodide;Tri-Iodode Anion;Triatomic iodide anion(1-);Iodide (I31-);UNII-DA1N05631Q;DA1N05631Q;14900-04-0;triiodide;TRIIODIDE(1-);D08RKK;D0U1SE;DTXSID40164150;Q1446811;I3;I3M

Chemical Property of Triiodide Ion

Chemical Property:

• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 380.7134
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: I[I-]I

Technology Process of Triiodide Ion

There total 88 articles about Triiodide Ion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → triiodide(1-) (14900-04-0,65219-61-6,721396-52-7,78414-31-0,91117-61-2,63443-32-3)

Guidance literature:

With sodium acetate; acetic acid; In ethanol; N,N-dimethyl-formamide; byproducts: C6H9(OH)(CON(CH3)C6H10N), H2O; aerobic, 30°C; detected spectrophotometrically; Kinetics;

DOI:10.1021/ja00346a057

Reference yield:

water (7732-18-5) + iodine (7553-56-2,12190-71-5,8031-47-8) → triiodide(1-) (14900-04-0,65219-61-6,721396-52-7,78414-31-0,91117-61-2,63443-32-3) + hydrogen iodide (10034-85-2)

Guidance literature:

In water; hydrolysis; with increasing of HI concn. and in presence of a precipitate reactn. to I3(1-);;

Reference yield:

iodide (14362-44-8,20461-54-5,69239-56-1) + hypochloric acid (14989-30-1,7790-92-3) → triiodide(1-) (14900-04-0,65219-61-6,721396-52-7,78414-31-0,91117-61-2,63443-32-3) + chloride (16887-00-6)

Guidance literature:

In water; acid assisted reaction with phosphate buffer at various pH; rates measured by pulsed-accelerated-flow method; Kinetics;

upstream raw materials:

iodine

water

iodide

pyridine

Downstream raw materials:

iodine

iodide

{Co(CO)3(P(C₆H₅)3)2}⁽¹⁺⁾*I₃^(1-)={Co(CO)3(P(C₆H₅)3)2}I₃

cadmium(II)

Refernces

• 1、 Bonifacic, Marija,Schoeneich, Christian,Asmus, Klaus-Dieter. "Halogenated Peroxyl Radicals as Multi-Electron Oxidants: Pulse Radiolysis Study on the Reaction of Trichloromethyl Peroxyl Radicals with Iodide". . p. 1117 - 1119. Retrieved 1991.
• 2、 Nakagawa, Keizo,Wang, Fumin,Murata, Yusuke,Adachi, Motonari. "Effect of acetylacetone on morphology and crystalline structure of nanostructured TiO2 in titanium alkoxide aqueous solution system". . p. 736 - 737. Retrieved 2005.
• 3、 Minns, Jason W.,Khan, Arshad. "α-cyclodextrin-I3- host-guest complex in aqueous solution: Theoretical and experimental studies". . p. 6421 - 6425. Retrieved 2002.
• 4、 Rodriguez-Mu?iz, Gemma M.,Gomez-Mendoza, Miguel,Nuin, Edurne,Andreu, Inmaculada,Marin, M. Luisa,Miranda, Miguel A.. " snorkelling : Vs. diving in mixed micelles probed by means of a molecular bathymeter". . p. 10281 - 10288. Retrieved 2017.
• 5、 Austin, Jack M.,Groenewald, Theo,Spiro, Michael. "Heterogeneous Catalysis in Solution. Part 18. The Catalysis by Carbons of Oxidation-Reduction Reactions". . p. 854 - 859. Retrieved 1980.
• 6、 Hirtenlehner, Christa,Krims, Charlotte,Hoelbling, Johanna,List, Manuela,Zabel, Manfred,Fleck, Michel,Berger, Raphael J. F.,Schoefberger, Wolfgang,Monkowius, Uwe. "Syntheses, crystal structures, reactivity, and photochemistry of gold(iii) bromides bearing N-heterocyclic carbenes". . p. 9899 - 9910. Retrieved 2011.
• 7、 Bhadra, Mayukh,Transue, Wesley J.,Lim, Hyeongtaek,Cowley, Ryan E.,Lee, Jung Yoon C.,Siegler, Maxime A.,Josephs, Patrick,Henkel, Gerald,Lerch, Markus,Schindler, Siegfried,Neuba, Adam,Hodgson, Keith O.,Hedman, Britt,Solomon, Edward I.,Karlin, Kenneth D.. "A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity". . p. 3707 - 3713. Retrieved 2021.
• 8、 Mills, Andrew,Williams, Geraint. "Ruthenium Dioxide Hydrate: Is it a Hydrogen Catalyst?". . p. 321 - 323. Retrieved 1989.
• 9、 Das, Dipanwita,Lee, Yong-Min,Ohkubo, Kei,Nam, Wonwoo,Karlin, Kenneth D.,Fukuzumi, Shunichi. "Acid-induced mechanism change and overpotential decrease in dioxygen reduction catalysis with a dinuclear copper complex". . p. 4018 - 4026. Retrieved 2013.
• 10、 Braathen, Geir,Chou, Pi-Tai,Frei, Heinz. "Time-Resolved Reaction of O2(1Δ) with I- in Aqueous Solution". . p. 6610 - 6615. Retrieved 1988.