Trimethyl(trichloromethyl)silane

Base Information

• Chemical Name: Trimethyl(trichloromethyl)silane
• CAS No.: 5936-98-1
• Molecular Formula: C4H9Cl3Si
• Molecular Weight: 191.56
• European Community (EC) Number: 844-888-5
• DSSTox Substance ID: DTXSID70391896
• Nikkaji Number: J143.990A
• Wikidata: Q82189678
• Mol file: 5936-98-1.mol

Synonyms:trichloromethyltrimethylsilane

Chemical Property of Trimethyl(trichloromethyl)silane

Chemical Property:

• Melting Point: 129-132°C
• Boiling Point: 146-156 °C(Press: 749 Torr)
• PSA: 0.00000
• Density: 1.164±0.06 g/cm3(Predicted)
• LogP: 3.65390
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 189.953910
• Heavy Atom Count: 8
• Complexity: 78.3

Purity/Quality:

98%Min ^*data from raw suppliers

trimethyl(trichloromethyl)silane ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C(Cl)(Cl)Cl

Technology Process of Trimethyl(trichloromethyl)silane

There total 7 articles about Trimethyl(trichloromethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

chloro-trimethyl-silane (75-77-4) + chloroform (67-66-3,8013-54-5) → dichloromethane (75-09-2) + trichloromethyltrimethylsilane (5936-98-1)

Guidance literature:

With hexaethylphosphoric triamide; In acetonitrile; at 20 ℃; for 144h;

Reference yield: 31.0%

chloro-trimethyl-silane (75-77-4) + chloroform (67-66-3,8013-54-5) → (dichloromethyl)trimethylsilane (5926-38-5) + trichloromethyltrimethylsilane (5936-98-1)

Guidance literature:

With tetrahydrofuran; magnesium; In hexane; for 4h; Heating;

Reference yield: 30.5%

chlorine (7782-50-5) + Chloromethyltrimethylsilane (2344-80-1) → (dichloromethyl)trimethylsilane (5926-38-5) + bis(chloromethyl)dimethylsilane (2917-46-6) + me2Si(me-Cl)(me-Cl2) (18171-70-5) + tris(chloromethyl)methylsilane (18171-72-7) + trichloromethyltrimethylsilane (5936-98-1)

Guidance literature:

In neat (no solvent); Irradiation (UV/VIS); irradiation of (CH3)3Si(CH2Cl) and gaseous Cl2 at about 60°C;; product mixt. obtained;;

DOI:10.1021/ja01146a099

upstream raw materials:

Chloromethyltrimethylsilane

tetrachloromethane

chloro-trimethyl-silane

chloroform

Downstream raw materials:

(1’,1’,1’-trichloro-3’-nitropropan-2’-yl)benzene

trimethylsilyl trifluoromethanesulfonate

1,1,1-trichloro-3-phenyl-2-butanol

1,1,1-trichloro-3-phenyl-2-butanol

Refernces

• 1、 Chaussard, Jacques,Folest, Jean-Claude,Nedelec, Jean-Yves,Perichon, Jacques,Sibille, Soline,Troupel, Michel. "Use of Sacrificial Anodes in Electrochemical Functionalization of Organic Halides". . p. 369 - 381. Retrieved 2007/10/02.
• 2、 Pons, P.,Biran, C.,Bordeau, M.,Dunogues, J.. "Electrosynthese en chimie organosilicique: silylation selective de polychloromethanes". . p. 31 - 38. Retrieved 2007/10/02.