1-Decanamine, N-methyl-

Base Information

• Chemical Name: 1-Decanamine, N-methyl-
• CAS No.: 7516-82-7
• Molecular Formula: C11H25N
• Molecular Weight: 171.326
• European Community (EC) Number: 856-357-5
• UNII: O694K7T3YS
• DSSTox Substance ID: DTXSID7074610
• Nikkaji Number: J313.819D
• Wikidata: Q27285403
• Mol file: 7516-82-7.mol

Synonyms:N-methyldecan-1-amine;7516-82-7;1-Decanamine, N-methyl-;METHYLDECYLAMINE;n-methyldecylamine;N-METHYL-N-DECYLAMINE;decyl-methyl-amine;N-Methyl-1-decanamine;UNII-O694K7T3YS;O694K7T3YS;decylmethylamine;decyl(methyl)amine;Methyl decyl amine;N-METHYLDECANAMINE;N-N-DECYLMETHYLAMINE;N-(DECYL)METHYLAMINE;SCHEMBL21188;DTXSID7074610;MFCD03551913;AKOS009024032;E80418;EN300-255578;Q27285403;Z102767086

Chemical Property of 1-Decanamine, N-methyl-

Chemical Property:

• Melting Point: 4-5 °C
• Boiling Point: 224 °C(Press: 775 Torr)
• PKA: 10.79±0.10(Predicted)
• PSA: 12.03000
• Density: 0.8028 g/cm3(Temp: 0 °C)
• LogP: 3.73740
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 171.198699802
• Heavy Atom Count: 12
• Complexity: 71.4

Purity/Quality:

97% ^*data from raw suppliers

N-METHYL-N-DECYLAMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCNC

Technology Process of 1-Decanamine, N-methyl-

There total 4 articles about 1-Decanamine, N-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

N-methyldecanoic acid amide (23220-25-9) → N-methyldecan-1-amine (7516-82-7) + N-methyldidecylamine (7396-58-9)

Guidance literature:

With α-Me3Si-γ-Me3SiO-poly[oxy(methylsilanediyl)]; (μ₃,η²,η³,η⁵-acenaphthylene)Ru(CO)7; In various solvent(s); at 40 ℃; for 24h;

DOI:10.1021/jo070591c

Reference yield: 16.0%

N-methyldecanoic acid amide (23220-25-9) → 1-Decanol (112-30-1) + N-methyldecan-1-amine (7516-82-7) + N-methyldidecylamine (7396-58-9)

Guidance literature:

With aluminium(III) triflate; [Ru(1,1,1-tris(di(3,5-dimethoxyphenyl)phosphino-methyl)ethane)(trimethylenemethane)]; hydrogen; In tetrahydrofuran; at 160 ℃; for 16h; under 75007.5 Torr;

Reference yield:

N,N-dimethyldecanamide (14433-76-2) → 1-Decanol (112-30-1) + N-methyldecan-1-amine (7516-82-7) + N,N-dimethyldecylamine (1120-24-7) + N-methyldidecylamine (7396-58-9)

Guidance literature:

With hydrogen; dimethyl amine; CuCr catalyst (Leuna 1970T); at 250 ℃; under 7500.75 Torr; Product distribution / selectivity;

upstream raw materials:

N-methyldecanoic acid amide

N,N-dimethyldecanamide

Refernces

• 1、 Hanada, Shiori,Ishida, Toshiki,Motoyama, Yukihiro,Nagashima, Hideo. "The ruthenium-catalyzed reduction and reductive N-alkylation of secondary amides with hydrosilanes: Practical synthesis of secondary and tertiary amines by judicious choice of hydrosilanes". . p. 7551 - 7559. Retrieved 2008/02/12.
• 2、 -. "PROCESS FOR OBTAINING AMINES BY REDUCTION OF AMIDES". Page/Page column 11-12. . Retrieved 2008/06/13.