Technology Process of Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin-ethinyl dimer
There total 2 articles about Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin-ethinyl dimer which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C48H47BrN4O8Zn;
With
oxygen;
In
dichloromethane;
for 0.25h;
With
copper(l) chloride;
In
dichloromethane;
for 0.0333333h;
With
N,N,N,N,-tetramethylethylenediamine;
for 0.333333h;
- Guidance literature:
-
With
air; copper(l) chloride;
In
dichloromethane;
stirring CH2Cl2 soln. of porphyrin deriv. in air for 15 min, addn. of CuCl, stirring for 2 min, addn. of amine deriv., stirring for 20 min; addn. of water, washing with water, chromy. (silica, CH2Cl2/methanol (98:2)), size exclusion chromy. (Bio Beads S-X1, THF), chromy. (silica, CH2Cl2/methanol (98.7:1.3)), recrystn. (CH2Cl2/pentane), NMR and MALDI;
DOI:10.1039/b814789b
- Guidance literature:
-
With
triethylamine; triphenylphosphine;
tris-(dibenzylideneacetone)dipalladium(0); copper(l) iodide;
In
N,N-dimethyl-formamide;
at 40 ℃;
for 3h;
