4-nitrophenyl 4-methoxybenzoate

Base Information

• Chemical Name: 4-nitrophenyl 4-methoxybenzoate
• CAS No.: 7464-46-2
• Molecular Formula: C14H11NO5
• Molecular Weight: 273.245
• Hs Code.: 2918990090
• Mol file: 7464-46-2.mol

Synonyms:p-Anisicacid, p-nitrophenyl ester (7CI,8CI);4-(4'-Methoxybenzoyloxy)nitrobenzene;4-Nitrophenyl 4-methoxybenzoate;4-Nitrophenyl 4'-methoxybenzoate;NSC 404070;p-Nitrophenyl p-anisate;p-Nitrophenyl p-methoxybenzoate;

Chemical Property of 4-nitrophenyl 4-methoxybenzoate

Chemical Property:

• Vapor Pressure: 3.16E-08mmHg at 25°C
• Refractive Index: 1.597
• Boiling Point: 448.2 °C at 760 mmHg
• Flash Point: 202.5 °C
• PSA: 81.35000
• Density: 1.309 g/cm³
• LogP: 3.34580
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

4-Nitrophenyl4-methoxybenzoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-nitrophenyl 4-methoxybenzoate

There total 12 articles about 4-nitrophenyl 4-methoxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + 4-methoxy-benzaldehyde (123-11-5) → p-nitrophenyl p-methoxybenzoate (7464-46-2)

Guidance literature:

With bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-1-ium chloride; palladium diacetate; sodium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; at 100 ℃; for 24h; Sealed tube;

DOI:10.1016/j.tetlet.2011.03.017

Reference yield: 90.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + 4-methoxybenzoic acid (100-09-4) → p-nitrophenyl p-methoxybenzoate (7464-46-2)

Guidance literature:

With TiO(acac)2; In xylene; for 34h; Heating;

DOI:10.1021/jo051337s

Reference yield: 89.0%

4-methoxybenzoic acid (100-09-4) + 4-nitrophenol acetate (830-03-5) → p-nitrophenyl p-methoxybenzoate (7464-46-2)

Guidance literature:

With dodecatungstosilic acid; In 5,5-dimethyl-1,3-cyclohexadiene; at 160 - 170 ℃; for 2.5h; Concentration; Reagent/catalyst; Reflux;

upstream raw materials:

4-methoxy-benzoyl chloride

4-nitrophenol sodium salt

4-nitro-phenol

4-methoxybenzoic acid

Downstream raw materials:

4-(4'-methoxybenzoyloxy)aniline

4-nitro-phenol

N-dodecyl-4-methoxybenzamide

ethyl 4-methoxybenzoate

Refernces

• 1、 Kim, Ju Hyun,Park, Hawon,Chung, Young Keun. "Rhodium-catalyzed synthesis of esters from aryl iodides and alcohols: use of alcohols with/without the assistance of aldehydes as carbon monoxide and nucleophile sources". . p. 190 - 194. Retrieved 2017/01/12.
• 2、 Dey, Soumen,Gadakh, Sunita K.,Sudalai. "Titanium superoxide-a stable recyclable heterogeneous catalyst for oxidative esterification of aldehydes with alkylarenes or alcohols using TBHP as an oxidant". . p. 10631 - 10640. Retrieved 2015/11/17.