Cu(1,2-bis(diphenylphosphane)benzene)(5,5'-diethynyl-2,2'-bipyridine)(ClO₄)*CH₂Cl₂

Base Information

• Chemical Name: Cu(1,2-bis(diphenylphosphane)benzene)(5,5'-diethynyl-2,2'-bipyridine)(ClO₄)*CH₂Cl₂
• CAS No.: 1360717-64-1
• Molecular Formula: CH₂Cl₂*C₄₄H₃₂CuN₂P₂*ClO₄
• Molecular Weight: 898.628
• Mol file: 1360717-64-1.mol

Synonyms:

Chemical Property of Cu(1,2-bis(diphenylphosphane)benzene)(5,5'-diethynyl-2,2'-bipyridine)(ClO₄)*CH₂Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cu(1,2-bis(diphenylphosphane)benzene)(5,5'-diethynyl-2,2'-bipyridine)(ClO₄)*CH₂Cl₂

There total 1 articles about Cu(1,2-bis(diphenylphosphane)benzene)(5,5'-diethynyl-2,2'-bipyridine)(ClO₄)*CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.8%

tetrakis(acetonitrile)copper(I) perchlorate (14057-91-1) + dichloromethane (75-09-2) + o-phenylenebis(diphenylphosphine) (13991-08-7) + 5,5'-diethynyl-2,2'-bipyridyl (162318-26-5) → Cu(1,2-bis(diphenylphosphane)benzene)(5,5'-diethynyl-2,2'-bipyridine)(ClO4)*CH2Cl2 (1360717-64-1)

Guidance literature:

In acetonitrile; byproducts: CH3CN; anhydrous and anaerobic conditions, Schlenk technique, Ar, room temp.; Cu-complex added to soln. of bipyridine and diphosphane, soln. stirred for 1 d at room temp., solvent removed (reduced pressure), CH2Cl2 added; soln. filtered, layered with n-hexane; elem. anal.;

DOI:10.1016/j.poly.2011.12.040

upstream raw materials:

tetrakis(acetonitrile)copper(I) perchlorate

dichloromethane

o-phenylenebis(diphenylphosphine)

5,5'-diethynyl-2,2'-bipyridyl

Refernces