trans-dichlorobis(dimethylsulfide)platinum(II)

Base Information

• Chemical Name: trans-dichlorobis(dimethylsulfide)platinum(II)
• CAS No.: 17457-51-1
• Molecular Formula: C₄H₁₂Cl₂PtS₂
• Molecular Weight: 390.257
• Mol file: 17457-51-1.mol

Synonyms:

Chemical Property of trans-dichlorobis(dimethylsulfide)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-dichlorobis(dimethylsulfide)platinum(II)

There total 38 articles about trans-dichlorobis(dimethylsulfide)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

trans-tetrachlorobis(dimethyl sulfide) platinum(IV) (16893-23-5,16893-33-7,55903-49-6) + methyl (triphenylphosphoranylidene)acetate (21204-67-1,2605-67-6) → trans-dichlorobis(dimethylsulfide)platinum(II) (17836-09-8,17457-51-1,55449-91-7) + (2-methoxy-2-oxoethyl)triphenylphosphonium chloride (2181-97-7) + Triphenylphosphine oxide (791-28-6)

Guidance literature:

In dichloromethane; Ph3P=CHCO2Me was added to soln. Pt(IV) complex in CH2Cl2, react. mixt. was kept at room temp. for 3 h; solvent was evapd., residue was chromed. on silica using CH2Cl2/Et2O (9:1) as eluent;

DOI:10.1021/ic000769c

Reference yield: 97.0%

hexachloroplatinic(IV) acid hydrate + dimethylsulfide (75-18-3) → dichlorobis(dimethylsulfide)platinum(II) (17457-51-1,17836-09-8,55449-91-7)

Guidance literature:

With N₂H₆Cl₂; In water; byproducts: Pt; addn. of hydrazinium salt to aqueous soln. of platinum compd., heating at 100°C for 0.5 h, cooling to room temp., filtration, addn. of dimethyl sulfide, heating to 80°C; cooling, extn. (CH2Cl2), drying over MgSO4, evapn., NMR;

DOI:10.1021/om0610039

Reference yield: 93.0%

potassium tetrachloroplatinate(II) (10025-99-7) + dimethylsulfide (75-18-3) → dichlorobis(dimethylsulfide)platinum(II) (17457-51-1,17836-09-8,55449-91-7)

Guidance literature:

In water; N2 atmosphere; addn. of Me2S to a soln. of K2PtCl4 in degassed water, heating to 80°C for 45 min; cooling to room temp., extn. with CH2Cl2, drying combined CH2Cl2 layers with MgSO4, filtration, evapn. to dryness, drying in vacuo;

upstream raw materials:

potassium tetrachloroplatinate(II)

dimethylsulfide

hydrazine dihydrochloride

{Ptms₄}{PtCl₆}

Downstream raw materials:

dichloro(2,2'-bipyridine)platinum(II)

cis-dichlorobis(dimethylsulphide)platinum(II)

trans-dichlorobis(diethyl sulfide)platinum(II)

trans-dichlorobis[tris[3,5-bis(trifluoromethyl)phenyl]phosphane]platinum(II)

Refernces

• 1、 Otto, Stefanus,Roodt, Andreas. "Reactivity studies of trans-[PtClMe(SMe2)2] towards anionic and neutral ligand substitution processes". . p. 4626 - 4632. Retrieved 2006.
• 2、 Fard, Mahmood Azizpoor,Behnia, Ava,Puddephatt, Richard J.. "Cycloneophylplatinum Chemistry: A New Route to Platinum(II) Complexes and the Mechanism and Selectivity of Protonolysis of Platinum-Carbon Bonds". . p. 3368 - 3377. Retrieved 2018.
• 3、 Moret, Marc-Etienne,Chen, Peter. "Ligand binding energies in cationic platinum(II) complexes: A quantitative study in the gas phase". . p. 1523 - 1530. Retrieved 2008/10/09.