Diallyldichlorosilane

Base Information

• Chemical Name: Diallyldichlorosilane
• CAS No.: 3651-23-8
• Molecular Formula: C6H10 Cl2 Si
• Molecular Weight: 181.137
• Hs Code.: 2931900090
• European Community (EC) Number: 887-358-9
• DSSTox Substance ID: DTXSID9063114
• Nikkaji Number: J96.545F
• Wikidata: Q81990495
• Mol file: 3651-23-8.mol

Synonyms:DIALLYLDICHLOROSILANE;3651-23-8;Silane, dichlorodi-2-propenyl-;dichloro-bis(prop-2-enyl)silane;Silane, dichlorodi-2-propen-1-yl-;C6H10Cl2Si;silane, diallyldichloro-;SCHEMBL231601;DTXSID9063114;dichlorobis(prop-2-en-1-yl)silane;MFCD00048160;AKOS006282070;FT-0634946

Chemical Property of Diallyldichlorosilane

Chemical Property:

• Vapor Pressure: 2.83mmHg at 25°C
• Boiling Point: 162.5°Cat760mmHg
• Flash Point: 46.4°C
• PSA: 0.00000
• Density: 1.027g/cm³
• LogP: 3.27820
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 179.9928822
• Heavy Atom Count: 9
• Complexity: 97.6

Purity/Quality:

98%,99%, ^*data from raw suppliers

DIALLYLDICHLOROSILANE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC[Si](CC=C)(Cl)Cl

Technology Process of Diallyldichlorosilane

There total 3 articles about Diallyldichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-chloroprop-1-ene (107-05-1) → tetrachlorosilane (10026-04-7,53609-55-5) + allyldichlorosilane (3937-28-8) + allyltrichlorosilane (107-37-9) + diallyldichlorosilane (3651-23-8) + trichlorosilane (10025-78-2)

Guidance literature:

With Si-Cu; In neat (no solvent); Si-Cu (9:1) and allylchloride dild. by N2 at 250°C;;

DOI:10.1021/ja01226a058

Reference yield:

3-chloroprop-1-ene (107-05-1) → allyldichlorosilane (3937-28-8) + allyltrichlorosilane (107-37-9) + diallyldichlorosilane (3651-23-8)

Guidance literature:

at 250 ℃;

DOI:10.1021/ja01226a058

Reference yield:

allylmagnesium bromide (1730-25-2) → allyltrichlorosilane (107-37-9) + diallyldichlorosilane (3651-23-8) + 4-Chloro-4-(2-propenyl)-4-sila-1,6-heptadiene (17865-20-2) + tetraallylsilane (1112-66-9)

Guidance literature:

With tetrachlorosilane; In diethyl ether; at -100 ℃; for 16h;

DOI:10.1016/S0040-4020(01)89280-2

upstream raw materials:

allylmagnesium bromide

3-chloroprop-1-ene

Downstream raw materials:

1,1-diallyl-2,5-diphenyl-silolane

diallyl(dimethyl)silane

1,3-diallyl-1,1,3,3-tetramethyldisiloxane

Refernces