TETRAALLYLSILANE

Base Information

• Chemical Name: TETRAALLYLSILANE
• CAS No.: 1112-66-9
• Molecular Formula: C12H20Si
• Molecular Weight: 192.376
• Hs Code.: 29319090
• Mol file: 1112-66-9.mol

Synonyms:Silane,tetra-2-propenyl- (9CI);Tetraallylsilane;Silane, tetraallyl- (6CI,8CI);

Chemical Property of TETRAALLYLSILANE

Chemical Property:

• Appearance/Colour: Clear colorless to faintly yellow liquid
• Vapor Pressure: 0.304mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: 1.45
• Boiling Point: 208.682 °C at 760 mmHg
• Flash Point: 67.174 °C
• PSA: 0.00000
• Density: 0.793 g/cm³
• LogP: 4.17920
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Water Solubility.: Insoluble in water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetraallylsilane ≥97.0% (GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Uses: It is used in synthesis of dendrimers and as an intermediates.

Technology Process of TETRAALLYLSILANE

There total 20 articles about TETRAALLYLSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

allylmagnesium bromide (1730-25-2) → tetraallylsilane (1112-66-9)

Guidance literature:

With tetrachlorosilane; In diethyl ether; for 4h; Heating;

DOI:10.1039/C39920001400

Reference yield: 98.0%

allylsamarium bromide (346713-20-0) → tetraallylsilane (1112-66-9)

Guidance literature:

With tetrachlorosilane; In tetrahydrofuran; at 20 ℃; for 0.5h;

DOI:10.1016/j.jorganchem.2006.07.023

Reference yield: 96.0%

3-chloroprop-1-ene (107-05-1) → tetraallylsilane (1112-66-9)

Guidance literature:

With tetrachlorosilane; magnesium; In tetrahydrofuran; hexane; at 65 ℃; for 3.5h; Inert atmosphere;

DOI:10.1021/ma300957d

upstream raw materials:

allylmagnesium bromide

allylmagnesium bromide

allyl bromide

sodiumtris(benzene-1,2 diolato)silicate

Downstream raw materials:

Si((CH₂)3Si(CH₃)2C₆H₅)4

(4S,1'S)-3-(1'-allyl-1'-phenylmethylamino)-4-phenylmethyl-2-oxazolidinone

Refernces

• 1、 Davidson et al.. "". . p. 1265,1266, 1267. Retrieved 1973.
• 2、 Rebrov,Leshchiner,Muzafarov. "Synthesis of carbosilane dendrimers with variable distance between branching nodes". . p. 8796 - 8804. Retrieved 2012.
• 3、 -. "METHOD FOR PRODUCING TETRAALKENYLSILANE". Paragraph 0024. . Retrieved 2020/06/27.
• 4、 -. "NOVEL SILICON COMPOUND AND POLYMER". Paragraph 0048-0050. . Retrieved 2016/10/07.