Methylisopropylideneamine

Base Information

• Chemical Name: Methylisopropylideneamine
• CAS No.: 6407-34-7
• Molecular Formula: C₄H₉N
• Molecular Weight: 71.1222
• Mol file: 6407-34-7.mol

Synonyms:Methylamine,N-isopropylidene- (6CI,7CI,8CI); 2-Methyliminopropane; Acetone N-methylimine;N-Isopropylidenemethylamine; N-Methyl-2-iminopropane; N-Methyl-2-propanimine;N-Methylacetone imine

Chemical Property of Methylisopropylideneamine

Chemical Property:

• Vapor Pressure: 203mmHg at 25°C
• Boiling Point: 60.8°C at 760 mmHg
• PSA: 12.36000
• Density: 0.72g/cm³
• LogP: 1.09700

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methylisopropylideneamine

There total 17 articles about Methylisopropylideneamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

N-tert-butyl-O-diphenylphosphinylhydroxylamine (79239-25-1) → methyl-1 ethylideneamine (6407-34-7,19885-74-6) + diphenyl-phosphinic acid (1707-03-5)

Guidance literature:

In chloroform; for 12h; Heating;

DOI:10.1055/s-1988-27749

Reference yield: 82.0%

2-methylamino-2-methylpropanenitrile (2273-39-4) → methyl-1 ethylideneamine (6407-34-7,19885-74-6)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; dicyclohexyl-carbodiimide; at 150 - 160 ℃;

DOI:10.1055/s-1981-29566

Reference yield: 63.0%

N-methylpropan-2-amine (4747-21-1) → methyl-1 ethylideneamine (6407-34-7,19885-74-6) + N-methylideneisopropylamine (77037-04-8)

Guidance literature:

With N-chloro-succinimide; Adipic acid; potassium tert-butylate; under 0.004 Torr; Title compound not separated from byproducts; 1.) 2 h, RT 2.) 2 h, 60 deg C;

DOI:10.1016/S0040-4020(01)86145-7

upstream raw materials:

acetone

methylamine

t-butyl azide

heptamethyldisilazane

Downstream raw materials:

2,4,6-Triisopropyl-1-methyl-1H-indole

6-methyl-1,2-dimethylindole

1,2-dimethylindole

1,2,4,6,-tetramethylindole

Refernces

• 1、 Su, Xiaoming,Panariti, Persi,Abboud, Khalil A.,McElwee-White, Lisa. "Bis(β-ketoiminate) dioxo tungsten(VI) complexes as precursors for growth of WOx by aerosol-assisted chemical vapor deposition". . p. 219 - 227. Retrieved 2019/06/05.
• 2、 Egawa,Ito,Konaka. "Reactions of N, N-dichloroalkylamines with solid base as studied by FTIR combined with DFT calculations". . p. 337 - 344. Retrieved 2007/10/03.