Trimethylsulfonium hydroxide

Base Information

• Chemical Name: Trimethylsulfonium hydroxide
• CAS No.: 17287-03-5
• Molecular Formula: C3H9S.HO
• Molecular Weight: 94.1778
• Hs Code.: 2930909090
• European Community (EC) Number: 628-493-3
• UNII: 835839L58Y
• DSSTox Substance ID: DTXSID70938225
• Wikidata: Q1559354
• Mol file: 17287-03-5.mol

Synonyms:trimethylsulfonium;trimethylsulfonium chloride;trimethylsulfonium hydroxide;trimethylsulfonium iodide;trimethylsulfonium nitrate;trimethylsulphonium chloride

Chemical Property of Trimethylsulfonium hydroxide

Chemical Property:

• Flash Point: 11oC
• PSA: 48.36000
• Density: 0.81
• LogP: 0.31730
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 94.04523611
• Heavy Atom Count: 5
• Complexity: 8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trimethylsulfonium Hydroxide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,T
• Hazard Codes: F,T
• Statements: 11-23/24/25-34-39/23/24/25
• Safety Statements: 26-36/37/39-45-36/37-16-7

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[S+](C)C.[OH-]

Technology Process of Trimethylsulfonium hydroxide

There total 2 articles about Trimethylsulfonium hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.1%

trimethylsulfonium chloride (3086-29-1) → trimethylsulphonium hydroxide (17287-03-5)

Guidance literature:

With sodium hydroxide; In methanol; at -5 - 5 ℃; for 2h; Temperature; Solvent;

Reference yield:

trimethylsulphonium iodide (2181-42-2) → trimethylsulphonium hydroxide (17287-03-5)

Guidance literature:

With silver(l) oxide;

DOI:10.1046/j.1468-3148.2000.00035.x

Reference yield: 81.0%

3,5-dichlorobenzoic acid (51-36-5) + trimethylsulphonium hydroxide (17287-03-5) → methyl 3,5-dichlorobenzoate (2905-67-1)

Guidance literature:

In ethyl acetate; at 20 ℃; for 2h;

DOI:10.1016/S0045-6535(97)00205-1

upstream raw materials:

trimethylsulphonium iodide

trimethylsulfonium chloride

Downstream raw materials:

3-Methyl-2'-desoxy-uridin

2-amino-9-(2-deoxy-β-D-erythro-pentofuranosyl)-6-methoxypurine

N¹-methyl-2'-deoxyguanosine

7-Methyl-2'-deoxyguanosine

Refernces

• 1、 Yamauchi,K. et al.. "-". . p. 638 - 639. Retrieved 1979.
• 2、 -. "Buffer compositions". Page column 9. . Retrieved 2008/06/13.