ZINC;prop-1-ene

Base Information

• Chemical Name: ZINC;prop-1-ene
• CAS No.: 1802-55-7
• Molecular Formula: C6H10Zn
• Molecular Weight: 147.535
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID10336524
• Mol file: 1802-55-7.mol

Synonyms:zinc;prop-1-ene;1802-55-7;Zinc, di-2-propenyl-;DTXSID10336524

Chemical Property of ZINC;prop-1-ene

Chemical Property:

• Melting Point: 85 °C (sublm)
• PSA: 0.00000
• LogP: 2.01050
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 146.007392
• Heavy Atom Count: 7
• Complexity: 4.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH2-]C=C.[CH2-]C=C.[Zn+2]

Technology Process of ZINC;prop-1-ene

There total 6 articles about ZINC;prop-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

zinc(II) chloride (7646-85-7,24359-56-6) + allylmagnesium bromide (1730-25-2) → diallylzinc (1802-55-7)

Guidance literature:

In diethyl ether; byproducts: MgBrCl;

DOI:10.1016/S0022-328X(00)81022-0

Reference yield: 78.0%

allylmagnesium bromide (2622-05-1) + zinc(II) chloride (7646-85-7,24359-56-6) → diallylzinc (1802-55-7)

Guidance literature:

In diethyl ether; byproducts: MgCl2;

DOI:10.1016/S0022-328X(00)81022-0

Reference yield: 10.0%

zinc(II) chloride (7646-85-7,24359-56-6) + allylmagnesium bromide (1730-25-2) → 2-allylpropane-1,3-diylzinc + diallylzinc (1802-55-7)

Guidance literature:

In diethyl ether; byproducts: MgBr2; to suspn. of ZnCl2 in ether prop-2-enylmagnesium bromide added at -20°C for 4 h, after 12 h MgBr2 filtered, solvent evapd. at -10°C 1 Torr, residue stand at 35-40°C/0.0001 Torr for 6 h; bis(prop-2-enyl)zinc sublimed, residue extd. with toluene-d8;

DOI:10.1016/S0022-328X(00)81022-0

upstream raw materials:

allylmagnesium bromide

zinc(II) chloride

allylmagnesium bromide

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Downstream raw materials:

1-phenylpent-4-en-2-ol

2-phenyl-pent-4-en-1-ol

hex-5-en-2-ol

(Z)-5-Allyl-6-iodo-dec-5-ene

Refernces

• 1、 Rauser, Marian,Ascheberg, Christoph,Niggemann, Meike. "Direct Reductive N-Functionalization of Aliphatic Nitro Compounds". supporting information. p. 3970 - 3974. Retrieved 2018/02/26.
• 2、 Cui, Yi,Li, Wei,Sato, Takehiro,Yamashita, Yasuhiro,Kobayashi, Shu. "Catalytic use of zinc amide for transmetalation with allylboronates: General and efficient catalytic allylation of carbonyl compounds, imines, and hydrazones". supporting information. p. 1193 - 1205. Retrieved 2013/06/04.