4-Hepten-1-ol

Base Information

• Chemical Name: 4-Hepten-1-ol
• CAS No.: 24469-79-2
• Molecular Formula: C7H14O
• Molecular Weight: 114.188
• Hs Code.: 2905290000
• European Community (EC) Number: 958-269-3
• Nikkaji Number: J142.150F,J99.916D
• Mol file: 24469-79-2.mol

Synonyms:4-Hepten-1-ol;(E)-hept-4-en-1-ol;Hept-4-en-1-ol;24469-79-2;4-Hepten-1-ol, (4E)-;(4E)-HEPT-4-EN-1-OL;20851-55-2;SCHEMBL295928;CHEBI:188367;CUKAXHVLXKIPKF-ONEGZZNKSA-N;CS-0356819;EN300-378175;EN300-1854777

Chemical Property of 4-Hepten-1-ol

Chemical Property:

• Boiling Point: 174℃
• Flash Point: 69℃
• PSA: 20.23000
• Density: 0.844
• LogP: 1.72510
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 114.104465066
• Heavy Atom Count: 8
• Complexity: 57.4

Purity/Quality:

99%, ^*data from raw suppliers

4-Hepten-1-ol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC=CCCCO
• Isomeric SMILES: CC/C=C/CCCO

Technology Process of 4-Hepten-1-ol

There total 10 articles about 4-Hepten-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C9H21NO2 (98096-53-8) → heptene-4 ol-1 (6191-71-5,24469-79-2,20851-55-2) + N,N-dimethylhydroxylamine (5725-96-2) + dimethylamino-5 heptanol-1 (44977-19-7) + heptene-5 ol-1 (89794-36-5)

Guidance literature:

Product distribution; Heating;

Reference yield:

trans-3-chloro-2-ethyltetrahydropyran (31535-06-5,39193-16-3,59777-08-1) → (E)-hept-4-en-1-ol (24469-79-2) + (Z)-4-hepten-1-ol (6191-71-5)

Guidance literature:

With samarium diiodide; In tetrahydrofuran; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Heating;

DOI:10.1016/S0040-4039(00)82388-6

Reference yield:

4,5-Dibromheptanol (78076-10-5) → (E)-hept-4-en-1-ol (24469-79-2) + (Z)-4-hepten-1-ol (6191-71-5)

Guidance literature:

With tetrabutylammonium tetrafluoroborate; In N,N-dimethyl-formamide; Yield given. Yields of byproduct given; -1.4 V (vs. SCE) at a mercury pool (divided cell);

DOI:10.1016/S0040-4039(01)92506-7

upstream raw materials:

4-oxobutyl acetate

n-propyltriphenylphosphonium bromide

C₉H₂₁NO₂

Hepten-3-saeure-ethylester

Downstream raw materials:

(+/-)-(3a,6-trans; 3a,7a-cis)-6-ethyl-4-(hydroxymethyl)-2,3,3a,6,7,7a-hexahydro-1H-indene-4-carboxylate

(E)-tetradec-11-en-1-yl acetate

(E)-11-tetradecen-1-ol

14-tetrahydropyranyloxy-2(E)-tetradecene

Refernces

• 1、 Crombie, Leslie,Rainbow, Linda J.. "Stereoselective Synthesis of Alcohols containing (Z)- and (E)-Olefins, Dienes, Enynes and Styrenes: Cyclic β-Halogeno Scissions using Samarium Diiodide as the Electron-transfer Agent". . p. 673 - 688. Retrieved 2007/10/02.
• 2、 Barbry, Didier,Hasiak, Bruno,Augait, Jean-Michel,Couturier, Daniel. "EVOLUTION THERMIQUE DE N-OXYDES DE DIMETHYLAMINO-5 ALCANOLS-1 SUBSTITUES EN 5. COMPETITION ENTRE REARRANGEMENTS DE COPE ET DE MEISENHEIMER". . p. 956 - 961. Retrieved 2007/10/02.