GLYPHOSATE-N-METHYL

Base Information

• Chemical Name: GLYPHOSATE-N-METHYL
• CAS No.: 24569-83-3
• Molecular Formula: C4H10NO5P
• Molecular Weight: 183.101
• Mol file: 24569-83-3.mol

Synonyms:Glycine,N-methyl-N-(phosphonomethyl);GLY008;[Methyl(phosphonomethyl)amino]acetic acid;N-methyl N-phosphonomethylglycine;N-(phosphonomethyl)-N-methyl glycine;Methyl Glyphosate;Glycine (N-methyl-N-(phosphonomethyl)-(8Cl;N-(dihydroxyphosphorylmethyl)sarcosine;

Chemical Property of GLYPHOSATE-N-METHYL

Chemical Property:

• Melting Point: 223-224 °C
• Boiling Point: 427.9±55.0 °C(Predicted)
• PKA: 1.21±0.10(Predicted)
• Flash Point: 100?°C
• PSA: 107.88000
• Density: 1.583±0.06 g/cm3(Predicted)
• LogP: -0.86200

Purity/Quality:

98%Min ^*data from raw suppliers

MethylGlyphosate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Glyphosate (G765000) impurity in the pesticide sample.

Technology Process of GLYPHOSATE-N-METHYL

There total 4 articles about GLYPHOSATE-N-METHYL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phosphonomethylimino-di-acetic acid (5994-61-6) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + formic acid (64-18-6) + Aminomethylphosphonic acid (1066-51-9) + N-methylaminomethanephosphonic acid (35404-71-8) + N-methyl N-phosphonomethylglycine (24569-83-3) + N-(phosphonemethyl)glycine (1071-83-6) + Phosphate (14265-44-2,264888-19-9)

Guidance literature:

With oxygen; In water; at 100 ℃; Reagent/catalyst; Flow reactor;

Reference yield:

N-<(dimethoxyphosphinyl)methyl>glycine (65886-96-6) → hydroxymethylphosphonic acid (2617-47-2) + <<(carboxymethyl)imino>dimethylene>bisphosphonic acid (2439-99-8) + N-methyl N-phosphonomethylglycine (24569-83-3) + N-(phosphonemethyl)glycine (1071-83-6)

Guidance literature:

With hydrogenchloride; Yield given. Yields of byproduct given;

Reference yield:

→ <<(carboxymethyl)imino>dimethylene>bisphosphonic acid (2439-99-8) + N-methyl N-phosphonomethylglycine (24569-83-3) + N-(phosphonemethyl)glycine (1071-83-6) + glycine (56-40-6,18875-39-3,25718-94-9)

Guidance literature:

With sodium hydroxide; In water; at 24 - 85 ℃; for 105h; pH=3.11 - 3.57;

With hydrogenchloride; In water; at 25 - 85 ℃; for 3.25h; pH=0.67 - 1.66; Purification / work up;

upstream raw materials:

phosphonomethylimino-di-acetic acid

N-<(dimethoxyphosphinyl)methyl>glycine

Refernces

• 1、 -. "PURIFICATION OF N-(PHOSPHONOMETHYL)GLYCINE". Page/Page column 4, 7. . Retrieved 2008/06/13.
• 2、 Strunin, B. P.,Khizbullin, F. F.. "SYNTHESIS OF N-(PHOSPHONOMETHYL)GLYCINE". . p. 1992 - 1996. Retrieved 2007/10/02.