ETHYL 6-HEPTENOATE 98

Base Information

• Chemical Name: ETHYL 6-HEPTENOATE 98
• CAS No.: 25118-23-4
• Molecular Formula: C9H16O2
• Molecular Weight: 156.225
• Hs Code.: 2916190090
• Mol file: 25118-23-4.mol

Synonyms:6-Heptenoic acid,ethyl ester;Hept-6-ensaeure-aethylester;6-Heptensaeure-ethylester;ethyl hept-7-enoate;hept-6-enoic acid ethyl ester;Ethyl 6-heptenoate;

Chemical Property of ETHYL 6-HEPTENOATE 98

Chemical Property:

• Vapor Pressure: 0.576mmHg at 25°C
• Refractive Index: n20/D 1.426(lit.)
• Boiling Point: 189oC(lit.)
• Flash Point: 175 °F
• PSA: 26.30000
• Density: 0.89 g/mL at 25oC(lit.)
• LogP: 2.29590

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ethyl hept-6-enoate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of ETHYL 6-HEPTENOATE 98

There total 34 articles about ETHYL 6-HEPTENOATE 98 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

ethyl 2-(pyrimidin-2-ylsulfonyl)hept-6-enoate (288400-62-4) → ethyl 6-heptenoate (25118-23-4)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tributyltin chloride; In toluene; for 3h; Heating;

DOI:10.1021/jo000342n

Reference yield: 88.0%

Allyl acetate (591-87-7) + Ethyl 4-bromobutyrate (2969-81-5) → ethyl 6-heptenoate (25118-23-4)

Guidance literature:

Allyl acetate; With manganese; trifluoroacetic acid; cobalt(II) bromide; In acetonitrile; at 20 ℃; for 0.0833333h;

Ethyl 4-bromobutyrate; With pyridine; In acetonitrile; at 80 ℃; for 16h;

DOI:10.1002/anie.201104390

Reference yield: 75.0%

ethyl 7-hydroxyheptanoate (6149-48-0) → ethyl 6-heptenoate (25118-23-4)

Guidance literature:

With alumina; at 350 ℃; Temperature; Reagent/catalyst;

upstream raw materials:

ethyl hept-6-ynoate

ethyl 7-chloroheptanoate

potassium ethyl xanthogenate

2-(ethoxycarbonyl)hept-6-enoic acid

Downstream raw materials:

1-benzenesulfonyloct-7-en-2-one

ethyl heptanoate

2-(8-hydroxy-1-oxooctyl)-3,5-dihydroxybenzeneacetic acid ethyl ester

6,8-dichlorooctanoic acid ethyl ester

Refernces

• 1、 -. "Method for preparing 6,8-dichloroethyl caprylate". . . Retrieved 2021/03/13.
• 2、 Dachavaram, Soma Shekar,Kalyankar, Kondbarao Balasaheb,Das, Saibal. "First stereoselective total synthesis of Neocosmosin A: A facile approach". . p. 5629 - 5631. Retrieved 2014/12/11.