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CAS No.: | 3126-63-4 |
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Name: | Pentaerythritol glycidyl ether |
Article Data: | 8 |
Molecular Structure: | |
Formula: | C17H28 O8 |
Molecular Weight: | 360.405 |
Synonyms: | Oxirane,2,2'-[[2,2-bis[(oxiranylmethoxy)methyl]-1,3-propanediyl]bis(oxymethylene)]bis-(9CI); Propane, 1,3-bis(2,3-epoxypropoxy)-2,2-bis[(2,3-epoxypropoxy)methyl]-(7CI,8CI); 1,1,1,1-Tetra(glycidyloxymethyl)methane; Pentaerythritol glycidylether; Pentaerythritol tetraglycidyl ether |
EINECS: | 221-507-5 |
Density: | 1.269 g/cm3 |
Boiling Point: | 483.5 °C at 760 mmHg |
Flash Point: | 199.3 °C |
Safety: | Human mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors. |
PSA: | 87.04000 |
LogP: | -0.36560 |
Conditions | Yield |
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With 3-chloro-benzenecarboperoxoic acid In chloroform at 22℃; for 72.67h; | 92% |
With 3-chloro-benzenecarboperoxoic acid In chloroform at 22℃; for 72h; | 92% |
With 3-chloro-benzenecarboperoxoic acid In chloroform at 22℃; for 72h; | 91% |
With sodium silicate; dihydrogen peroxide In methanol; water; acetonitrile at 40℃; for 9h; Solvent; Reagent/catalyst; Temperature; Time; Concentration; Inert atmosphere; | 62% |
Conditions | Yield |
---|---|
With sodium hydroxide In water at 20 - 50℃; for 30h; | 86% |
With potassium hydroxide In dimethyl sulfoxide at 20 - 35℃; for 7h; | 37% |
With potassium hydroxide In dimethyl sulfoxide at 35℃; for 7h; | 79 % Chromat. |
Conditions | Yield |
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With potassium hydroxide In dimethyl sulfoxide | A 78% B 15% |
Conditions | Yield |
---|---|
With potassium hydroxide In water; dimethyl sulfoxide at 15 - 20℃; Cooling with ice; | A n/a B 60% C n/a |
With potassium hydroxide In dimethyl sulfoxide at 15 - 20℃; | A n/a B 45% C n/a |
Conditions | Yield |
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With potassium permanganate; KOH In diethyl ether; dimethyl sulfoxide; epichlorohydrin |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: potassium hydroxide; tetrabutylammomium bromide / tetrahydrofuran / 24 h / 70 °C 2: 3-chloro-benzenecarboperoxoic acid / chloroform / 72 h / 22 °C View Scheme | |
Multi-step reaction with 2 steps 1: potassium hydroxide; tetrabutylammomium bromide / tetrahydrofuran / 24 h / 70 °C 2: 3-chloro-benzenecarboperoxoic acid / chloroform / 72 h / 22 °C View Scheme |
Conditions | Yield |
---|---|
In methanol at 22 - 45℃; for 48.17h; | 99% |
piperazine
pentaerythritol tetraglycidyl ether
pentaerythritol tetra(2-hydroxypropyl-3-piperazine)
Conditions | Yield |
---|---|
In methanol at 25℃; for 24.08h; | 97% |
4-ethoxycarbonylpiperazine
pentaerythritol tetraglycidyl ether
pentaerythritol tetra(2-hydroxy-3-piperazine-N-ethyl carboxylate)
Conditions | Yield |
---|---|
In methanol at 25℃; for 1.33333h; | 95% |
pentaerythritol tetraglycidyl ether
pentaerythritol tetra(2-propanol-3-azide) ether
Conditions | Yield |
---|---|
With sodium azide; ammonium chloride In water; N,N-dimethyl-formamide at 50℃; | 95% |
With sodium azide; ammonium chloride In water; N,N-dimethyl-formamide at 50℃; Reflux; | 95% |
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1. | cyt-hmn:lym 7 mg/L | EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401M St., S.W., Washington, DC 20460) History Unknown 8EMQ-0787-0685 . | ||
2. | msc-ham:lng 6 mg/L | EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401M St., S.W., Washington, DC 20460) History Unknown 8EMQ-0787-0685 . |