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846032-36-8

Basic Information
CAS No.: 846032-36-8
Name: 4-Bromo-2-Indanone
Article Data: 3
Molecular Structure:
Molecular Structure of 846032-36-8 (4-Bromo-2-Indanone)
Formula: C9H7 Br O
Molecular Weight: 211.058
Synonyms: 4-bromo-2-indanone;4-Bromo-1,3-dihydro-2H-inden-2-one;4-BROMO-INDAN-2-ONE;2-INDANONE,4-BROMO;4-Bromo-1H-inden-2(3H)-one;
Density: 1.608g/cm3
Boiling Point: 312.2ºC at 760 mmHg
Flash Point: 126.3ºC
PSA: 17.07000
LogP: 2.11680
Synthetic route
16657-07-1

4-bromo-3H-indene

846032-36-8

4-bromo-1,3-dihydro-2H-inden-2-one

Conditions
ConditionsYield
Stage #1: 4-bromo-3H-indene With 4-methylmorpholine N-oxide; osmium(VIII) oxide
Stage #2: With toluene-4-sulfonic acid
846032-36-8

4-bromo-1,3-dihydro-2H-inden-2-one

Conditions
ConditionsYield
With zinc(II) iodide In benzene at 0 - 20℃; Product distribution / selectivity; Inert atmosphere;
125114-77-4

7-bromo-2,3-dihydro-1H-inden-1-one

846032-36-8

4-bromo-1,3-dihydro-2H-inden-2-one

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: sodium tetrahydroborate / ethanol; dichloromethane / 3 h / 0 - 20 °C
2: toluene-4-sulfonic acid / toluene / 0.5 h / Reflux
3: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 3 h / 0 - 20 °C
4: zinc(II) iodide / toluene / 4 h / 0 - 20 °C
View Scheme

rac-7-bromo-2,3-dihydro-1H-inden-1-ol

846032-36-8

4-bromo-1,3-dihydro-2H-inden-2-one

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: toluene-4-sulfonic acid / toluene / 0.5 h / Reflux
2: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 3 h / 0 - 20 °C
3: zinc(II) iodide / toluene / 4 h / 0 - 20 °C
View Scheme
45738-35-0

4-bromo-indene

846032-36-8

4-bromo-1,3-dihydro-2H-inden-2-one

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 3 h / 0 - 20 °C
2: zinc(II) iodide / toluene / 4 h / 0 - 20 °C
View Scheme

C9H7BrO

846032-36-8

4-bromo-1,3-dihydro-2H-inden-2-one

Conditions
ConditionsYield
With zinc(II) iodide In toluene at 0 - 20℃; for 4h;
846032-36-8

4-bromo-1,3-dihydro-2H-inden-2-one

943749-58-4

8-bromo-1,4-dihydro-2H-isoquinolin-3-one

Conditions
ConditionsYield
With hydrogenchloride; sodium azide at 0 - 12℃; for 12.3333h;33%
846032-36-8

4-bromo-1,3-dihydro-2H-inden-2-one

846032-40-4

4-bromo-2,2-difluoro-indan

Conditions
ConditionsYield
With diethylamino-sulfur trifluoride
846032-36-8

4-bromo-1,3-dihydro-2H-inden-2-one

123324-71-0

4-tert-butylphenylboronic acid

4-(4-t-butylphenyl)-2-indanone

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 80℃; for 16h;
846032-36-8

4-bromo-1,3-dihydro-2H-inden-2-one

A

2-[2-(5-methylfuryl)]-4-(4-t-butylphenyl)indene

B

C24H24O

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / ethanol; toluene; water / 16 h / 80 °C
2.1: n-butyllithium / tetrahydrofuran / 4 h / -25 - 20 °C
2.2: 16 h / -25 - 20 °C
2.3: 0.17 h / Reflux
View Scheme
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Chemistry

Molecule structure of 4-Bromo-2-Indanone (CAS NO.846032-36-8):

Molecular Weight: 211.05528 g/mol
Molecular Formula: C9H7BrO