100020-03-9

Basic information

• Product Name: ((CH₃)3SiCH₂SeC₆H₅)2PtCl₂
• CAS NO: 100020-03-9
• Molecular Weight: 752.551
• Mol File: 100020-03-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((CH₃)3SiCH₂SeC₆H₅)2PtCl₂(CAS DataBase Reference)
• NIST Chemistry Reference: ((CH₃)3SiCH₂SeC₆H₅)2PtCl₂(100020-03-9)
• EPA Substance Registry System: ((CH₃)3SiCH₂SeC₆H₅)2PtCl₂(100020-03-9)

Safety Data

• Hazardous Substances Data: 100020-03-9(Hazardous Substances Data)

Upstream product

• 10025-99-7 potassium tetrachloroplatinate(II) 
• 56253-60-2 trimethyl-phenylselanylmethyl-silane 

Relevant articles and documents

Synthesis and characterization of Pd(II) and Pt(II) complexes of Me3MCH2SeR (M = Si, Ge; R = Me, Ph) and crystal structures of trans-(Me3SiCH2SeMe)2PdCl2 and trans-(Me3GeCH2SeMe)2PtCl2

Six complexes of the general formula (Me3MCH2SeR)2M′O2 (M = Si, Ge; R = Me, Ph; M′ = Pd, Pt) have been prepared. Spectroscopic results suggest that the complexes have trans geometry, which is confirmed by the single-crystal X-ray structure determination of two of them. The crystals of (Me3SiCH2SeMe)2PdCl2 (1) are orthorhombic, Pbca, with a = 6.492 (4) ?, b = 11.438 (7) ?, c = 27.247 (15) ?, Z = 4, and R = 0.0249. The crystals of (Me3GeCH2SeMe)2PtCl2 (2) are also orthorhombic, Pbca, with a = 6.451 (1) ?, b = 11.543 (2) ?, c = 27.457 (5) ?, Z = 4, and R = 0.0431. Compounds 1 and 2 are isostructural, and the configuration around selenium is pyramidal while around palladium or platinum it is square-planar. In solution, the molecules display pyramidal inversion at selenium.