56253-60-2 Usage
General Description
(Phenylselenomethyl)trimethylsilane is a type of organosilicon compound that combines silicon, selenium, methyl, and phenyl groups. As its name suggests, it contains three methyl groups (CH3) attached to the silicon atom, a phenyl group (C6H5) and a selenium atom. This chemical is primarily used in the field of organic synthesis. Its unique composition lends it certain properties that make it valuable in various chemical reactions. Like many organosilicon and organoselenium compounds, it must be handled with caution due to its reactivity and potential toxicity.
Check Digit Verification of cas no
The CAS Registry Mumber 56253-60-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,6,2,5 and 3 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 56253-60:
(7*5)+(6*6)+(5*2)+(4*5)+(3*3)+(2*6)+(1*0)=122
122 % 10 = 2
So 56253-60-2 is a valid CAS Registry Number.
InChI:InChI=1/C10H16SeSi/c1-12(2,3)9-11-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3
56253-60-2Relevant articles and documents
1-(organoselanyl)perfluoroalkanols: A stable and efficient precursor for organoselenols
Yamamoto, Terahisa,Moriura, Eri,Sawa, Arisa,Yoshimatsu, Mitsuhiro
scheme or table, p. 1046 - 1047 (2009/12/03)
The 1-(organoselanyl)perfluoroalkanols 1, 3, 4, and 10 were successfully prepared and reactions with hexanoyl chlorides to produce the corresponding esters 5, 7, and 8, accompanied by the selenoesters 6 were conducted. The DBU-mediated alkylations of the heptafluorobutanols 4, 10, and the α-p-nitro-benzoate 2 with alkyl halides easily provided alkyl phenyl selenides 9a-9i and 11a-11c in good to high yields. Copyright
TRANSFORMATION OF α-PHENYLSELENOKETONES TO ALLYLIC SELENIDES VIA MIGRATION OF THE PHENYLSELENO GROUP
Nishiyama, Hisao,Itagaki, Kazuyoshi,Osaka, Noriyuki,Itoh, Kenji
, p. 4103 - 4106 (2007/10/02)
α-Phenylselenoketones were readily converted to the allylic selenides by treatment with trimethylsilylmethyllithium and subsequent reaction with tin(II)chloride via a facile migration of the phenylseleno group in course of the reaction.
