107102-14-7

Basic information

• Product Name: 2,3-benzo-10-benzyl-10-aza-1,4,7,13-tetraoxa-2-cyclopentadecene
• Synonyms: 2,3-benzo-10-benzyl-10-aza-1,4,7,13-tetraoxa-2-cyclopentadecene
• CAS NO: 107102-14-7
• Molecular Weight: 357.45
• Mol File: 107102-14-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,3-benzo-10-benzyl-10-aza-1,4,7,13-tetraoxa-2-cyclopentadecene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-benzo-10-benzyl-10-aza-1,4,7,13-tetraoxa-2-cyclopentadecene(107102-14-7)
• EPA Substance Registry System: 2,3-benzo-10-benzyl-10-aza-1,4,7,13-tetraoxa-2-cyclopentadecene(107102-14-7)

Safety Data

• Hazardous Substances Data: 107102-14-7(Hazardous Substances Data)

Upstream product

• 100-44-7 benzyl chloride 
• 10234-40-9 2,2'-(1,2-phenylenedioxy)diethanol 
• 54535-06-7 bis(o-phenylene)glycol ditosylate 
• 101-32-6 N-benzyl-diethanolamine 

Downstream Products

• 54533-83-4 benzo-10-aza-15-crown-5 
• 123473-45-0 4'-formyl-2,3-benzo-10-benzyl-10-aza-1,4,7,13-tetraoxa-2-cyclopentadecene 

Relevant articles and documents

Synthesis of monoazacrown ethers under phase-transfer catalysis

A procedure has been proposed for the synthesis of monoazacrown ethers by reaction of N-benzyldiethanolamine with oligo(ethylene glycol) bis-p-toluenesulfonates in a two-phase system aromatic hydrocarbon-50% aqueous alkali, followed by removal of the benzyl group by catalytic hydrogenolysis. The maximal yields of N-benzylaza-12-crown-4, -18-crown-6, and -21-crown-7 were achieved by adding 4-10 equiv of LiCl, BaBr2, and CsCl, respectively, to the reaction mixture, which probably indicated template effect. Pleiades Publishing, Ltd., 2012.