122333-64-6

Basic information

• Product Name: trans-N-Methyl-5-phenyl-4-penten-1-amine
• Synonyms: trans-N-Methyl-5-phenyl-4-penten-1-amine
• CAS NO: 122333-64-6
• Molecular Weight: 175.274
• Mol File: 122333-64-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: trans-N-Methyl-5-phenyl-4-penten-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: trans-N-Methyl-5-phenyl-4-penten-1-amine(122333-64-6)
• EPA Substance Registry System: trans-N-Methyl-5-phenyl-4-penten-1-amine(122333-64-6)

Safety Data

• Hazardous Substances Data: 122333-64-6(Hazardous Substances Data)

Upstream product

• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 28525-69-1 (4E)-5-phenyl-4-pentenoic acid 
• 22768-07-6 (E)-ethyl 5-phenylpent-4-enoate 
• 131529-91-4 (E)-5-Phenyl-pent-4-enoic acid methylamide 
• 63082-55-3 diethyl (E)-cinnamyl malonate 

Downstream Products

• 36939-28-3 N-methyl-2-phenylpiperidine 
• 122333-70-4 cis-N-Methyl-5-phenyl-4-penten-1-amine 
• 4266-03-9 N-Methyl-2-(phenylmethyl)pyrrolidine 
• 51498-40-9 trans-N,N-dimethyl-5-phenyl-4-penten-1-amine 

Relevant articles and documents

Phosphazene base-catalyzed hydroamination of aminoalkenes for the construction of isoindoline scaffolds: Application to the total synthesis of aristocularine

A method for isoindoline synthesis via phosphazene base-catalyzed intramolecular hydroamination of aminoalkenes was developed. The reaction has a broad functional group tolerance, including for halide, cyano, and methoxy groups, and could also be used to

INTRAMOLECULAR PHOTOCHEMICAL REACTIONS OF N-ALKYL-5-PHENYL-4-PENTEN-1-AMINES

Irradiation of N-alkyl-5-phenyl-4-penten-1-amines results in the formation of intramolecular styrene-amine adducts and disproportionation products.Increasing the bulk of the N-alkyl group increases the regioselectivity of N-H transfer favoring the formation of piperidine vs. pyrrolidine products and favors disproportionation vs. cyclization.