63082-55-3

Basic information

• Product Name: Propanedioic acid, [(2E)-3-phenyl-2-propenyl]-, diethyl ester
• CAS NO: 63082-55-3
• Molecular Formula: C16H20O4
• Molecular Weight: 276.332
• Mol File: 63082-55-3.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, [(2E)-3-phenyl-2-propenyl]-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, [(2E)-3-phenyl-2-propenyl]-, diethyl ester(63082-55-3)
• EPA Substance Registry System: Propanedioic acid, [(2E)-3-phenyl-2-propenyl]-, diethyl ester(63082-55-3)

Safety Data

• Hazardous Substances Data: 63082-55-3(Hazardous Substances Data)

Upstream product

• 996-82-7 sodium diethylmalonate 
• 4392-24-9 Cinnamyl bromide 
• 14990-09-1 tert-butyl cinnamate 
• 66684-75-1 diethyl 2-[3-phenylprop-2-en-1-ylidene]propanedioate 
• 2327-99-3 1-phenylpropadiene 
• 105-53-3 diethyl malonate 
• 7757-82-6 sodium sulfate 
• 104-55-2 3-phenyl-propenal 
• 85217-69-2 cinnamyl methyl carbonate 
• 300-57-2 allylbenzene 
• 1586-98-7 (2,3-dibromopropyl)benzene 
• 100-42-5 styrene 
• 2049-80-1 (2-propenyl)propanedioic acid diethyl ester 
• 103-54-8 cinnamyl acetate 

Downstream Products

• 1332643-08-9 diethyl 2-cinnamyl-2-(4-methylpenta-2,3-dienyl)malonate 
• 1256264-99-9 C₂₁H₂₄O₄ 
• 1228111-28-1 diethyl 2-(2-(chloromethyl)allyl)-2-cinnamylmalonate 
• 1187458-42-9 2-((Z)-3-methyl-pent-2-en-4-ynyl)-2-((E)-3-phenyl-allyl)-malonic acid diethyl ester 
• 1187458-44-1 2-((Z)-3-ethynyl-oct-2-enyl)-2-((E)-3-phenyl-allyl)-malonic acid diethyl ester 
• 1187458-65-6 2-((E)-3-phenyl-allyl)-2-((E)-3-phenyl-pent-2-en-4-ynyl)-malonic acid diethyl ester 
• 181181-19-1 2-Cinnamyl-4-pentynoic acid 
• 126377-32-0 α-(3-phenyl-2-trans-propenyl)-1H-imidazole-4-ethanamine 
• 126377-42-2 ethyl α-(3-phenyl-2-trans-propenyl)-1H-imidazole-4-propanoate 
• 126377-44-4 5,6,7,8-tetrahydro-5-oxo-7-(3-phenyl-2-trans-propenyl)imidazo<1,5-c>pyrimidine 
• 126377-46-6 α-(3-phenyl-2-trans-propenyl)-1H-imidazole-4-butanoic acid 
• 126377-43-3 α-(3-phenyl-2-trans-propenyl)-1H-imidazole-4-propanoic acid 
• 133100-03-5 (E)-1-diazo-6-phenyl-5-hexen-2-one 
• 122333-64-6 trans-N-Methyl-5-phenyl-4-penten-1-amine 

Relevant articles and documents

Pd(0)-catalyzed allylic alkylation/Heck coupling in domino sequence

A new molecular queuing process has been achieved, in which a single Pd-based catalytic system promotes two unrelated, sequential catalytic cycles in chronologically distinct order. This study demonstrates also that allylic alkylations can be catalyzed by the Herrmann's phosphapalladacycle, a result that further supports the involvement of a Pd(0) species in its mechanism of action.

Derivatives of phosphorous acid as a new class of ligands for Pd-catalyzed allylation

Amido- and aminophosphites and hydrospirophosphoranes can be used as ligands in the Pd-catalyzed allylation of ethyl malonate with ethyl (3-phenylprop-2-enyl) carbonate. Bidentate ligands (RO)2P - O(CH2)n - NR′2

Highly selective palladium-benzothiazole carbene-catalyzed allylation of active methylene compounds under neutral conditions

The Pd-benzothiazol-2-ylidene complex I was found to be a chemoselective catalyst for the Tsuji-Trost allylation of active methylene compounds carried out under neutral conditions and using carbonates as allylating agents. The proposed protocol consists in a simplified procedure adopting an in situ prepared catalyst from Pd2dba3 and 3-methylbenzothiazolium salt V as precursors. A comparison of the performance of benzothiazole carbene with phosphanes and an analogous imidazolium carbene ligand is also proposed.

Metathesis transformations of unsaturated derivatives of β-diketones

Selected β-diketones bearing unsaturated derivatives have been demonstrated to undergo homo-metathesis and cross-metathesis with selected olefins in the presence of Grubbs catalysts. The reactions led to respective homo- and cross-metathesis products mainly with good yields and selectivities. Versita Sp. z o.o.