1315320-39-8Relevant articles and documents
Direct chemoselective allylation of inert amide carbonyls
Oda, Yukiko,Sato, Takaaki,Chida, Noritaka
supporting information; experimental part, p. 950 - 953 (2012/04/18)
Direct allylation of inert amide carbonyls utilizing the Schwartz reagent afforded either substituted tertiary or secondary amines. A preactivation step was successfully avoided, which is generally a requisite to increase the electrophilicity of amides. The reaction exhibited remarkable functional group tolerance and proceeded even in the presence of methyl esters and nitro groups.