135987-50-7Relevant articles and documents
Palladium/Me3SiOTf-catalyzed bis-silylation of α,β-unsaturated carbonyl compounds without involving oxidative addition of disilane
Ogoshi, Sensuke,Tomiyasu, Sadayuki,Morita, Masaki,Kurosawa, Hideo
, p. 11598 - 11599 (2002)
In the presence of a catalytic amount of Me3SiOTf and palladium(0), the addition of disilane to α,β-unsaturated carbonyl compounds proceeds under very mild conditions via η3-siloxyallylpalladium generated by the reaction of enone, en
Oxidative [1,2]-Brook Rearrangements Exploiting Single-Electron Transfer: Photoredox-Catalyzed Alkylations and Arylations
Deng, Yifan,Liu, Qi,Smith, Amos B.
, p. 9487 - 9490 (2017/07/24)
Oxidative [1,2]-Brook rearrangements via hypervalent silicon intermediates induced by photoredox-catalyzed single-electron transfer have been achieved, permitting the formation of reactive radical species that can engage in alkylations and arylations.
Copper-catalyzed addition of nucleophilic silicon to aldehydes
Cirriez, Virginie,Rasson, Corentin,Hermant, Thomas,Petrignet, Julien,Diaz Alvarez, Jesus,Robeyns, Koen,Riant, Olivier
, p. 1785 - 1788 (2013/04/10)
How to train your silane: A new family of chiral copper(I) complexes that bear a bifluoride counteranion were prepared and used in the first example of the enantioselective transfer of a silyl group to an aldehyde. This procedure provides fast access to non-racemic α-hydroxysilanes in high enantioselectivities. Copyright
