13694-42-3

Basic information

• Product Name: (+/-)-cylohexylphenylmethyl hydroperoxide
• Synonyms: (+/-)-cylohexylphenylmethyl hydroperoxide
• CAS NO: 13694-42-3
• Molecular Weight: 206.285
• Mol File: 13694-42-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-cylohexylphenylmethyl hydroperoxide(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-cylohexylphenylmethyl hydroperoxide(13694-42-3)
• EPA Substance Registry System: (+/-)-cylohexylphenylmethyl hydroperoxide(13694-42-3)

Safety Data

• Hazardous Substances Data: 13694-42-3(Hazardous Substances Data)

Upstream product

• 1944-01-0 1-benzylcyclohexan-1-ol 
• 4714-09-4 1-benzylcyclohexene 
• 945-49-3 cyclohexylphenylmethanol 
• 4410-75-7 (cyclohexylmethyl)benzene 

Relevant articles and documents

Kinetic resolution of hydroperoxides with enantiopure phosphines: Preparation of enantioenriched tertiary hydroperoxides

An efficient reductive kinetic resolution strategy capable of accessing optically active tertiary hydroperoxides is reported. Readily accessible tertiary hydroperoxides are resolved with commercially available (R)- or (S)-xylyl-PHANEPHOS with selectivity factors as large as 37. The resulting bis(phosphine oxide) can be recycled in high yields. The isolated mono(phosphine oxide) intermediate resolved hydroperoxides with the same selectivity as the parent bisphosphine. Copyright