4714-09-4

Basic information

• Product Name: Benzene, (1-cyclohexen-1-ylmethyl)-
• Synonyms: 1-cyclohexenyl-methyl-benzene;Cyclohex-1-enyl-phenyl-methan;cyclohex-1-enyl-phenyl-methane;1-benzyl-1-cyclohexene;1-benzyl-cyclohexene
• CAS NO: 4714-09-4
• Molecular Formula: C13H16
• Molecular Weight: 172.27
• Mol File: 4714-09-4.mol
• Article Data: 18

Chemical Properties

• Boiling Point: 139-141 °C(Press: 22 Torr)
• Density: 0.964 g/cm3
• CAS DataBase Reference: Benzene, (1-cyclohexen-1-ylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1-cyclohexen-1-ylmethyl)-(4714-09-4)
• EPA Substance Registry System: Benzene, (1-cyclohexen-1-ylmethyl)-(4714-09-4)

Safety Data

• Hazardous Substances Data: 4714-09-4(Hazardous Substances Data)

Upstream product

• 100-51-6 benzyl alcohol 
• 110-83-8 cyclohexene 
• 10503-37-4 7-phenylbicyclo[4.1.0]heptane 
• 1589-82-8 phenylmagnesium bromide 
• 108-94-1 cyclohexanone 
• 100-39-0 benzyl bromide 
• 87413-32-9 (cyclohex-2-enylsulfonyl)benzene 
• 6921-34-2 benzylmagnesium chloride 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 1192-37-6 methylenecyclohexane 
• 1449-46-3 benzyltriphenylphosphonium bromide 
• 28075-50-5 cyclohex-1-en-1-yl trifluoromethane sulfonate 
• 945-49-3 cyclohexylphenylmethanol 
• 1944-01-0 1-benzylcyclohexan-1-ol 

Downstream Products

• 101429-21-4 1-(2-benzyl-cyclohex-1-enyl)-propan-1-one 
• 861008-61-9 4-Hydroxy-1-(1-benzyl-cyclohexyl)-benzol 
• 13225-66-6 1,2,3,4-Tetrahydro-9-phenylanthracene 
• 81523-06-0 2-benzyl-cis-2-methoxy-r-1-cyclohexanol 
• 81523-05-9 2-benzyl-trans-2-methoxy-r-1-cyclohexanol 
• 34492-10-9 1-benzyl-r-1,t-2-cyclohexane-1,2-diol 
• 81523-04-8 1-benzyl-trans-2-methoxy-r-1-cyclohexanol 
• 50648-70-9 trans-2-benzylidenecyclohexanol 
• 946-33-8 2-benzylcyclohexan-1-one 
• 227464-44-0 2-benzyl-2-bromocyclohexan-1-one 
• 81523-07-1 2-benzyl-2-methoxycyclohexanone 
• 946-33-8 (R)-2-benzylcyclohexanone 
• 946-33-8 (S)-2-benzylcyclohexanone 
• 13694-42-3 (+/-)-cylohexylphenylmethyl hydroperoxide 

Relevant articles and documents

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Nickel-Catalyzed Cross-Coupling of Anisoles with Alkyl Grignard Reagents via C-O Bond Cleavage

Nickel-catalyzed cross-coupling of methoxyarenes with alkyl Grignard reagents, which involves the cleavage of the C(aryl)-OMe bond, has been developed. The use of 1,3-dicyclohexylimidazol-2-ylidene as a ligand allows the introduction of a variety of alkyl groups, including Me, Me3SiCH2, ArCH2, adamantyl, and cyclopropyl. The method can also be used for the alkylative elaboration of complex molecules bearing a C(aryl)-OMe bond.

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