14032-03-2Relevant articles and documents
Regioselective Chlorothiolation of Alkenes with Sulfonyl Chlorides
Wei, Jingjing,Liang, Shuaishuai,Jiang, Lvqi,Mumtaz, Yasir,Yi, Wen-Bin
, p. 977 - 984 (2019/12/25)
Newly developed sulfonyl chloride-based regioselective chlorothiolation of alkenes has been disclosed; the reaction is compatible with a variety of functional groups and can be scaled up to the gram scale with no loss in yield. The employment of readily a
Lewis acids as co-reagents in sulfenylation reactions
Zyk,Gavrilova,Mukhina,Bondarenko,Zefirov
experimental part, p. 608 - 610 (2011/07/29)
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Highly stereoselective chlorination of β-substituted cyclic alcohols using PPh3-NCS: Factors that control the stereoselectivity
Jaseer,Naidu, Ajay B.,Kumar, Sreehari S.,Rao, R. Koteshwar,Thakur, Krishna G.,Sekar
, p. 867 - 869 (2007/10/03)
A variety of trans-β-substituted cyclic alcohols were stereoselectively chlorinated to either the corresponding cis-chloride or trans-chloride (inversion or retention of configuration) with good to excellent yields; the stereochemical outcome is determined by the size of the ring and the nature of the β-substituents, especially the electronegativity of the substituted atom. The Royal Society of Chemistry.