1446696-23-6Relevant articles and documents
Nickel-Catalysed Allylboration of Aldehydes
Dennis, Francesca M.,Partridge, Benjamin M.,Robertson, Craig C.
, p. 1903 - 1914 (2020/07/04)
A nickel catalyst for the allylboration of aldehydes is reported, facilitating the preparation of homoallylic alcohols in high diastereoselectivity. The observed diastereoselectivities and NMR experiments suggest that allylation occurs through a well-defined six-membered transition state, with nickel acting as a Lewis acid.