2749-98-6

Basic information

• Product Name: Benzene, 1-chloro-4-(1,2-propadienyl)-
• CAS NO: 2749-98-6
• Molecular Formula: C9H7Cl
• Molecular Weight: 150.608
• Mol File: 2749-98-6.mol
• Article Data: 26

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-(1,2-propadienyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-(1,2-propadienyl)-(2749-98-6)
• EPA Substance Registry System: Benzene, 1-chloro-4-(1,2-propadienyl)-(2749-98-6)

Safety Data

• Hazardous Substances Data: 2749-98-6(Hazardous Substances Data)

Upstream product

• 637-87-6 1-Chloro-4-iodobenzene 
• 53915-69-8 allenyltributylstannane 
• 38365-51-4 1,1-dibromo-2-(4-chlorophenyl)cyclopropane 
• 925-90-6 ethylmagnesium bromide 
• 106-39-8 bromochlorobenzene 
• 50-00-0 formaldehyd 
• 3240-10-6 (4-chlorophenyl)propiolic acid 
• 70090-69-6 1-chloro-4-(prop-2-yn-1-yl)benzene 
• 1073-67-2 4-vinylbenzyl chloride 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 106-96-7 propargyl bromide 
• 75-25-2 Bromoform 
• 104-88-1 4-chlorobenzaldehyde 
• 29805-11-6 1-(4-chlorophenyl)prop-2-yn-1-ol 

Downstream Products

• 1234935-61-5 2-(dimethylphenylsilyl)-3-(4-chlorophenyl)-2-propene 
• 1234935-59-1 (3-(4-chlorophenyl)prop-1-en-2-yl)dimethyl(phenyl)silane 
• 1402235-32-8 2-(3-(4-chlorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1446696-23-6 4,4,5,5-tetramethyl-2-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-1,3,2-dioxaborolane 
• 1600528-34-4 (E)-1,2-dichloro-3-(4-chlorophenyl)-2-propene 
• 1600528-37-7 2,3-dichloro-3-(4-chlorophenyl)-1-propene 
• 1600528-31-1 (Z)-1-chloro-4-(2,3-dichloroprop-1-en-1-yl)benzene 
• 60691-90-9 3-bromo-1-(p-chlorophenyl)-1-propene 
• 1600528-40-2 (Z)-1,2-dibromo-3-(4-chlorophenyl)-2-propene 
• 1364457-03-3 (E)-1,2-dibromo-3-(4-chlorophenyl)-2-propene 
• 1600528-45-7 (Z)-1,2-diiodo-3-(4-chlorophenyl)-2-propene 
• 1600528-49-1 (E)-1,2-diiodo-3-(4-chlorophenyl)-2-propene 
• 1644189-11-6 N¹,N¹,N³,N³-tetrabenzyl-2-(4-chlorobenzylidene)propane-1,3-diamine 

Relevant articles and documents

Photoredox Catalyzed Sulfonylation of Multisubstituted Allenes with Ru(bpy)3Cl2 or Rhodamine B

A highly regio- and stereoselective sulfonylation of allenes was developed that provided direct access to α, β-substituted unsaturated sulfone. By means of visible-light photoredox catalysis, the free radicals produced by p-toluenesulfonic acid reacted with multisubstituted allenes to obtain Markovnikov-type vinyl sulfones with Ru(bpy)3Cl2 or Rhodamine B as photocatalyst. The yield of this reaction could reach up to 91%. A series of unsaturated sulfones would be used for further transformation to some valuable compounds.

Photoredox-Catalyzed α-Aminoalkylcarboxylation of Allenes with CO2

The photoredox-catalyzed α-aminoalkylcarboxylation of aryl allenes with CO2 and N,N-dimethylanilines is reported for the first time (26 examples, up to 96% yield). In the case of electron-deficient allenes, good regioselectivity was observed (up to 94:6), exclusively generating kinetic products over thermodynamic products. This protocol is a novel synthetic method for highly functionalized β,γ-unsaturated γ-aminobutyric esters.

Copper(ii)-catalyzed protoboration of allenes in aqueous media and open air

A method has been developed for the facile Cu(ii)-catalyzed protoboration of monosubstituted allenes in aqueous media under atmospheric conditions. The reaction occurs site selectively, favoring internal alkene protoboration to afford 1,1-disubstituted vinylboronic acid derivatives (up to 93?:?7) with modest to good yields. The method has been applied to a variety of phenylallene derivatives as well as alkyl-substituted allenes. This journal is